131496-20-3Relevant academic research and scientific papers
One-pot synthesis of phenacyl esters from acetophenone, [Bmim]Br 3, and potassium salts of carboxylic acids under solvent-free conditions
Le, Zhang-Gao,Xie, Zong-Bo,Xu, Jian-Ping
, p. 743 - 747 (2009)
One-pot synthesis of phenacyl esters from acetophenone, [Bmim]Br3, and potassium salts of carboxylic acids under solvent-free conditions gave the corresponding phenacyl esters with excellent yields. Copyright Taylor & Francis Group, LLC.
I2/TBHP-mediated oxidative coupling of ketones and toluene derivatives: a facile method for the preparation of α-benzoyloxy ketones
Chen, Cui,Liu, Weibing,Zhou, Peng,Liu, Hailing
, p. 20394 - 20397 (2017/04/19)
An efficient oxidative approach was developed for the α-benzoyloxylation of ketones using tert-butyl hydroperoxide (TBHP). This process provided facile access to a wide range of α-benzoyloxy ketones in good to excellent yields via the direct oxidative α-benzoyloxylation of a structurally diverse series of ketones using simple arylmethane compounds.
Oxidation-hydroxymethylation-reduction: A one-pot three-step biocatalytic synthesis of optically active α-aryl vicinal diols
Shanmuganathan, Saravanakumar,Natalia, Dessy,Greiner, Lasse,Dominguez De Maria, Pablo
scheme or table, p. 94 - 97 (2012/03/26)
A one-pot multi-step approach comprising enzymatic oxidation- hydroxymethylation-reduction enables the synthesis of optically active α-aryl vicinal diols with high yields and enantioselectivities. Formaldehyde required for the hydroxymethylation step is enzymatically produced in situ using less hazardous methanol as substrate.
Organic Reactions in Ionic Liquids: Ionic Liquid-Accelerated Nucleophilic Substitution Reaction of α-Tosyloxyketones with Potassium Salts of Aromatic Acids
Liu, Zhi,Chen, Zhen-Chu,Zheng, Qin-Guo
, p. 33 - 36 (2007/10/03)
The room temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) is used as a 'green' recyclable alternative to classical molecular solvents for the nucleophilic substitution reaction of α-tosyloxy ketones with pota
D-Fructose- and L-sorbose-derived endo- and exo-hydroxyglycal esters and some of their chemistry
Boettcher, Andrea,Lichtenthaler, Frieder W.
, p. 2693 - 2701 (2007/10/03)
Dehydrobrominations of benzoylated β-d-fructopyranosyl and α-l-sorbo-pyranosyl bromides have been examined to obtain suitable conditions for effecting the elimination toward the exo- as well as the endo-positions. In the fructose case, exposure to DBU in
Oxidation of Aryl Alkyl Ketones to α-Acyloxy, α-(Camphorsulfonyloxy), or α-Hydroxy Derivatives Using Manganese(III) Acetate in Combination with Carboxylic Acids or (1S)-(+)-10-Camphorsulfonic Acid
Demir, Ayhan S.,Camkerten, Nurettin,Akgun, Hulya,Tanyeli, Cihangir,Mahasneh, Ali S.,Watt, David S.
, p. 2279 - 2289 (2007/10/02)
The α-oxidation of aryl alkyl ketones using manganese(III) acetate in the presence of various carboxylic acids and (1S)-(+)-10-camphorsulfonic acid provided a convenient synthesis of α-acyloxy, α-(10-camphorsulfonyloxy), and α-hydroxy derivatives in good yield.
