132127-28-7

Basic information

• Product Name: Silanamine, N-[(4-methoxyphenyl)methylene]-1,1,1-trimethyl-, (E)-
• CAS NO: 132127-28-7
• Molecular Formula: C11H17NOSi
• Molecular Weight: 207.348
• Mol File: 132127-28-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Silanamine, N-[(4-methoxyphenyl)methylene]-1,1,1-trimethyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, N-[(4-methoxyphenyl)methylene]-1,1,1-trimethyl-, (E)-(132127-28-7)
• EPA Substance Registry System: Silanamine, N-[(4-methoxyphenyl)methylene]-1,1,1-trimethyl-, (E)-(132127-28-7)

Safety Data

• Hazardous Substances Data: 132127-28-7(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 123-11-5 4-methoxy-benzaldehyde 
• 4039-32-1 lithium hexamethyldisilazane 

Downstream Products

• 132127-32-3 (3R,4S)-3-Triisopropylsilyloxy-4-(4-methoxyphenyl)-2-azetidinone 
• 51208-43-6 meso-1,2-bis-(p-methoxyphenyl)-ethylenediamine 
• 181528-74-5 (-)-(2R,3S,6S)-2-hydroxymethyl-3-methyl-6-p-methoxyphenyl-4-piperidone 
• 188425-29-8 (1S)-1-(4-methoxyphenyl)but-3-en-1-amine 
• 145654-57-5 (3S,4R)-3-Benzyloxy-4-(4-methoxy-phenyl)-azetidin-2-one 
• 117106-36-2 d,l-1,2-diamino-1,2-bis(4-methoxyphenyl)ethane 
• 341979-62-2 3-methoxy-2-(4-methoxy-phenyl)-2,5-dihydro-1H-pyrrole 
• 183718-81-2 (E)-N-(4-methoxybenzylidene)benzamide 

Relevant articles and documents

EuFOD-catalyzed Hetero-Diels-Alder (HDA) reaction under microwave heating

An efficient EuFOD-catalyzed hetero-Diels-Alder reaction between azadienes and aldehydes under microwave irradiation is reported. The reaction proceeds under microwave heating with 5 mol% of EuFOD in 45-83% yields. Georg Thieme Verlag Stuttgart.

Lewis acid-catalyzed electrocyclization of 2-aza-1,3-butadienes to NH-β-lactams

Lewis acid-catalyzed cyclization of 2-aza-3-trimethylsilyloxy-buta-1,3-diene is reported. Stereochemical differences with the uncatalyzed cyclization are discussed.

Reversal of stereochemistry in a two-step Staudinger reaction by changing the backbone protecting group. Synthesis of NH-trans-3-benzoyloxy-4-aryl-azetidinones

Changing the protecting group in the glyoxylic acid derived ketene from benzyloxy to benzoyloxy provides a simple way of switching the diastereoselectivity of the substituents on the final β-lactam ring from cis to trans.