132680-48-9

Basic information

• Product Name: Carbamic acid, diethyl-, 4-methylphenyl ester
• CAS NO: 132680-48-9
• Molecular Formula: C12H17NO2
• Molecular Weight: 207.272
• Mol File: 132680-48-9.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Carbamic acid, diethyl-, 4-methylphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, diethyl-, 4-methylphenyl ester(132680-48-9)
• EPA Substance Registry System: Carbamic acid, diethyl-, 4-methylphenyl ester(132680-48-9)

Safety Data

• Hazardous Substances Data: 132680-48-9(Hazardous Substances Data)

Upstream product

• 124-38-9 carbon dioxide 
• 109-89-7 diethylamine 
• 123726-16-9 bis(4-methylphenyl)iodonium trifluoromethanesulfonate 
• 106-44-5 p-cresol 
• 88-10-8 N,N-diethylcarbamyl chloride 

Downstream Products

• 1025324-55-3 2-but-2-ynoyl-4-methylphenyl diethylcarbamate 
• 1245824-46-7 4-methyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl N,N-diethylcarbamate 
• 1595-01-3 1-hexyl-4-methyl-benzene 
• 474353-19-0 N,N-diethyl-2-hydroxy-5-methylbenzamide 
• 1450-72-2 5-methyl-2-hydroxyacetophenone 
• 2096-86-8 p-Tolylaceton 
• 167283-32-1 N-(p-tolyl)indole 
• 25372-10-5 1-p-tolyl-1H-imidazole 
• 195062-57-8 p-tolylboronic pinacol ester 
• 4714-21-0 4-methylstilbene 
• 613-33-2 (4,4'-dimethyl-1,1'-biphenyl) 
• 644-08-6 4-Methylbiphenyl 
• 3644-91-5 (4-methylphenyl)triethylsilane 
• 16155-94-5 6-methyl-2-p-tolylbenzoxazole 

Relevant articles and documents

Access to Biphenyls by Palladium-Catalyzed Oxidative Coupling of Phenyl Carbamates and Phenols

The oxidative cross-coupling of phenols (3 equiv) to various substituted phenyl N, N -diethylcarbamates was explored with a variety of substrates. Pd(OAc) 2 was employed as the catalyst (20 molpercent) and K 2 S 2 O 8

C-O Bond Silylation Catalyzed by Iron: A General Method for the Construction of Csp2-Si Bonds

The iron-catalyzed construction of Csp2-Si bonds via unreactive C-O bonds possesses a challenging topic in organic chemistry. Herein we report an iron-catalyzed silylation of aryl and alkenyl carbamates via C-O bond activation. This protocol fe

N -Arylation of (hetero)arylamines using aryl sulfamates and carbamates via C-O bond activation enabled by a reusable and durable nickel(0) catalyst

An effective and general aryl amination protocol has been developed using a magnetically recoverable Ni(0) based nanocatalyst. This new stable catalyst was prepared on Fe3O4@SiO2 modified by EDTA and investigated by FT-IR, EDX, TEM, XRD, DLS, FE-SEM, XPS, NMR, TGA, VSM, ICP and elemental analysis techniques. The reaction proceeded via carbon-oxygen bond cleavage of (hetero)aryl carbamates and sulfamates under simple and mild conditions without the use of any external ligands. This method demonstrated functional group tolerance in the N-arylation of various nitrogen-containing compounds as well as aliphatic amines, anilines, pyrroles, pyrazoles, imidazoles, indoles, and indazoles with good to excellent yields. Furthermore, the catalyst could be easily recovered by using an external magnetic field and directly reused at least six times without notable reduction in its activity. This journal is