5936-98-1Relevant academic research and scientific papers
POLYMETHYLATION OF ORGANOCHLOROSILANES
Podol'skii, A. V.,Khonina, T. G.,Lyampasova, T. P.,Kodess, M. I.
, p. 1476 - 1480 (2007/10/03)
Polychloromethylation of Me3SiCl, Me2PhSiCl, Me2SiCl2, and MePhSiCl2 in the system magnesium-chloroform-THF has been studies under mild conditions (in the temperature renge 60 -65 deg C), and a scheme of formation of the main and by-products has been proposed.
Use of Sacrificial Anodes in Electrochemical Functionalization of Organic Halides
Chaussard, Jacques,Folest, Jean-Claude,Nedelec, Jean-Yves,Perichon, Jacques,Sibille, Soline,Troupel, Michel
, p. 369 - 381 (2007/10/02)
This article reviews the new possibilities in organic synthesis offered by the electroreduction of organic halides in the presence of various electrophiles using sacrificial metallic anodes.
Electrosynthese en chimie organosilicique: silylation selective de polychloromethanes
Pons, P.,Biran, C.,Bordeau, M.,Dunogues, J.
, p. 31 - 38 (2007/10/02)
Silylation by electroreduction of carbon tetrachloride, chloroform or methylene chloride is more selective than the common organometallic route.Me3SiCCl3 (94percent) and (Me3Si)2Cl2 (68percent) were thus obtained from CCl4, Me3SiCHCl2, (94percent) and (Me3Si)2CHCl (56percent) from CHCl3 and Me3SiCH2Cl (90percent) from CH2Cl2.Complete silylation of polychloromethanes was also successful by electrosynthesis and gave satisfactory yields.
EINTOPFSYNTHESE TRICHLOROMETHYLSUBSTITUIERTER ALKOHOLE
Brunner, Henri,Wimmer, Peter
, p. C4 - C6 (2007/10/02)
A new one-pot synthesis of alcohols RCH(OH)CCl3 starting from CCl4, Me3SiCl, Mg and aldehydes RCHO is described.
