13280-00-7Relevant articles and documents
Hart,Schlosberg
, p. 5030 (1966)
Novel Regioselective Chlorination of Aliphatic Ketones via Mono-organothallium(III) Derivates
Glaser, Julius,Toht, Imre
, p. 1336 - 1337 (1986)
Room temperature reaction of simple aliphatic ketones with an aqueous solution of TiCl3 leads to mono-oxoalkylthalium(III) derivatives followed by formation of selectively α-monochlorinated ketones.
PROCESS FOR PREPARATION OF MOLINDONE
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Paragraph 0059, (2020/08/30)
The present invention provides process for preparation of molindone (I) comprising: a) reacting compound with cyclohexane-1,3-dione to form 2-(2-oxopentan-3-yl)cyclohexane-1,3-dione wherein X is Cl, Br or I, b) cyclizing 2-(2-oxopentan-3-yl)cyclohexane-1,
CYCLOBUTENEDIONE DERIVATIVES
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Page/Page column 51, (2010/12/17)
The present invention relates to compounds of the formula (I): to pharmaceutically acceptable salts therefore and to pharmaceutically acceptable solvates of said compounds and salts, wherein the substituents are defined herein; to compositions containing such compounds; and to the uses of such compounds in the treatment of various diseases, particularly inflammatory conditions.
A Convenient Synthesis of 3-Chloro-2-alkanones
Kimpe, Norbert De,Brunet, Pascal
, p. 595 - 596 (2007/10/02)
3-Chloro-2-alkanones were regiospecifically synthesized from methyl 2-alkyl-3-oxobutanoates by chlorination to afford methyl 2-alkyl-2-chloro-3-oxobutanoates followed by demethoxycarbonylation in acid medium.