132815-96-4Relevant academic research and scientific papers
Electrophilic Trifluoromethyl- and Fluoroalkylselenolation of Organometallic Reagents
Glenadel, Quentin,Ismalaj, Ermal,Billard, Thierry
, p. 530 - 533 (2017/02/05)
Fluoroalkylseleno groups are emerging groups that still suffer from a lack of efficient methods for introduction onto organic molecules. Herein, we describe an efficient method to perform reactions between in situ formed fluoroalkaneselenyl chlorides and organometallic reagents. With this strategy, various fluoroalkylselenolated molecules were easily obtained. Furthermore, the Hansch parameter of the CF3Se group was determined for the first time.
Perfluoroalkylphosphines and arsines obtained by Pd-catalyzed cross-coupling reaction with organoheteroatom stannanes
Lanteri, Mario N.,Rossi, Roberto A.,Martín, Sandra E.
experimental part, p. 3425 - 3430 (2010/01/18)
Pd-catalyzed cross-coupling reaction of organoheteroatom stannanes containing elements of the groups 15 (P, As) and 16 (Se) with perfluoroalkyl iodides (RfI) was studied. Herein, a one-pot two-step reaction to form P-Rf, As-Rf/
A convenient access to perfluoroalkyl selenoethers selenyl chlorides
Magnier,Vit,Wakselman
, p. 1260 - 1262 (2007/10/03)
The treatment of diselenides with different perfluoroalkyl iodides in the presence of sodium hydroxymethanesulfinate led to perfluoroalkyl selenides in fair to good yields. The reaction between benzyl perfluorooctyl selenide chlorine, or sulfuryl chloride
PERFLUOROALKYL-SELENATION OF OLEFINS
Uneyama, Kenji,Kitagawa, Kouichi
, p. 375 - 378 (2007/10/02)
Perfluoroalkyl-selenation of olefins has been performed by the reaction of diphenyl diselenide with sodium borohydride followed with perfluoroalkyl halides (RfX) and olefins where one electron transfer from phenylseleno anion to RfX occurs, generating per
