1329426-07-4

Upstream product

• 73183-34-3 bis(pinacol)diborane 
• 654065-52-8 1-bromo-3,4,5-tris-n-dodecyloxybenzene 
• 16492-75-4 5-bromo-1,2,3 trihydroxybenzene 
• 2675-79-8 1-bromo-3,4,5-trimethoxybenzene 
• 61676-62-8 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Downstream Products

• 1329426-12-1 2,4,6-tris[5-(3,4,5-tridodecyloxyphenyl)thiophen-2-yl]-1,3,5-triazine 
• 1365116-02-4 4-(3,4,5-tridodecyloxyphenyl)quinoline 
• 1392490-53-7 4,4′-difluoro-2,6-dimethyl-5-(thien-2-yl)-3-{[5-(3,4,5-tridodecyloxy)phen-1-yl]thien-2-yl}-4-bora-3a,4a-diaza-s-indacene 
• 1279083-00-9 2,5-bis(3,4,5-tris(dodecyloxy)phenyl)pyridine 

Relevant academic research and scientific papers

Columnar Iridium(III) Metallomesogens Based on Polycatenar Pyridyltetrazolate with Ambipolar Carrier Mobility Behavior

In this paper, we have designed and synthesized a series of neutral liquid-crystalline iridium(III) complexes based on polycatenar 2,5-diphenylpyridine and pyridyltetrazolate derivatives. Iridium(III) complexes all display highly emissive behavior with photoluminescence quantum yields in the range of 0.45-0.66 and a maximum emission wavelength at ～563 nm. Hexagonal columnar mesophases of iridium(III) complexes can be obtained by changing the number and length of peripheral alkoxyl chains attached to a 2,5-diphenylpyridine ligand (main ligand) and a pyridyltetrazolate ligand (auxiliary ligand). Moreover, experimental results of the charge transport properties for these iridium(III) complexes, which were measured by the space charge limited-current method, exhibit ambipolar carrier mobility behavior. In particular, the liquid-crystalline iridium(III) complexes can self-organize into one-dimensional (1D) nanostructure after thermal annealing treatment in their liquid-crystalline phase. The devices based on liquid crystal film display improved charge transport behavior compared with that of the devices based on polycrystalline film, indicating 1D nanostructure is beneficial to charge carrier injection and transportation.

Ion-pair-based assemblies comprising pyrrole-pyrazole hybrids

Modified 3,5-dipyrrolylpyrazole (DPP) derivatives in their protonated form produce planar [2+2]-type complexes with trifluoroacetate (TFA) ions. These complexes serve as constituent components of ion-pair-based assemblies. An essential strategy for the co

Full-color tunable photoluminescent ionic liquid crystals based on tripodal pyridinium, pyrimidinium, and quinolinium salts

Color-tunable luminescent ionic liquid crystals have been designed as a new series of luminescent materials. To achieve tuning of emission colors, intramolecular charge transfer (ICT) character has been incorporated into tripodal molecules. A series of th

Electro-functional octupolar π-conjugated columnar liquid crystals

A series of propeller-shaped π-conjugated molecules based on 2,4,6-tris(thiophene-2-yl)-1,3,5-triazines has been designed and synthesized to obtain ambipolar charge-transporting liquid-crystalline materials. The 3-fold electron-donating aromatic units are attached to the electron-accepting triazine core, which forms electro-functional octupolar π-conjugated structures. These octupolar molecules self-organize into one-dimensional columnar nanostructures and exhibit ambipolar carrier transport behavior, which has been revealed by time-of-flight measurements. In this approach, electron-donor and acceptor electro-active segments are assembled individually in each column to give one-dimensional nanostructured materials with precisely tuned electronic properties. Their desirable electronic structures responsible for both hole and electron conductions have also been examined by cyclic voltammetry and theoretical calculations. The present results provide a new guideline and versatile approach to the design of ambipolar conductive nanostructured liquid-crystalline materials.