13303-10-1

Basic information

• Product Name: T -BUTYL-P-NITROPHENYL CARBONATE
• Synonyms: tert-butyl p-nitrophenyl carbonate;CARBONIC ACID TERT-BUTYL ESTER 4-NITRO-PHENYL ESTER;Carbonic acid (4-nitrophenyl)tert-butyl ester;Carbonic acid 1,1-dimethylethyl 4-nitrophenyl ester;Carbonic acid O-(4-nitrophenyl)O-tert-butyl ester;Carbonic acid tert-butyl 4-nitrophenyl ester;Carbonic acid tert-butyl(4-nitrophenyl) ester;Einecs 236-328-8
• CAS NO: 13303-10-1
• Molecular Formula: C₁₁H₁₃NO₅
• Molecular Weight: 239.22462
• EINECS: 236-328-8
• Product Categories: Aromatics Compounds;Aromatics;Isotope Labeled Compounds
• Mol File: 13303-10-1.mol
• Article Data: 24

Chemical Properties

• Boiling Point: 345.7°Cat760mmHg
• Flash Point: 147.8°C
• Appearance: /
• Density: 1.227g/cm³
• Vapor Pressure: 6.04E-05mmHg at 25°C
• Refractive Index: 1.525
• CAS DataBase Reference: T -BUTYL-P-NITROPHENYL CARBONATE(CAS DataBase Reference)
• NIST Chemistry Reference: T -BUTYL-P-NITROPHENYL CARBONATE(13303-10-1)
• EPA Substance Registry System: T -BUTYL-P-NITROPHENYL CARBONATE(13303-10-1)

Safety Data

• Hazardous Substances Data: 13303-10-1(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

InChI:InChI=1/C11H13NO5/c1-11(2,3)17-10(13)16-9-6-4-8(5-7-9)12(14)15/h4-7H,1-3H3

Upstream product

• 100-02-7 4-nitro-phenol 
• 264255-59-6 1-tert-butoxy-2-tert-butoxycarbonyl-1,2-dihydrophthalazine 
• 24424-99-5 di-tert-butyl dicarbonate 
• 149411-91-6 N-benzyloxycarbonyl cytosine 
• 404586-94-3 1-(tert-butoxy)-2-(tert-butoxy)carbonyl-1,2-dihydroisoquinoline 
• 53639-36-4 C₁₂H₁₁N₃O₁₀ 
• 7693-46-1 4-Nitrophenyl chloroformate 
• 75-65-0 tert-butyl alcohol 

Downstream Products

• 13139-15-6 N-tert-butoxycarbonyl-L-leucine 
• 13139-16-7 N-(tert-butyloxycarbonyl)-L-isoleucine 
• 5068-28-0 (2R)-3-benzylsulfanyl-2-tert-butoxycarbonylamino-propionic acid 
• 4530-20-5 BOC-glycine 
• 15761-39-4 1-(tert-butoxycarbonyl)-L-proline 
• 15761-38-3 L-N-Boc-Ala 
• 3744-87-4 N-t-butyloxycarbonyl-DL-alanine 
• 6404-29-1 6-(tert-butoxycarbonylamino)hexanoic acid 
• 7536-59-6 Boc-Glu(OBzl)-ONp 
• 7536-55-2 N-tert-butyloxycarbonylasparagine 
• 33741-79-6 Dl-2-t-butoxycarbonylamino-2-(2-naphthyl)-acetic acid 
• 13734-41-3 t-Boc-L-valine 
• 57260-71-6 1-t-Butoxycarbonylpiperazine 
• 1227157-27-8 t-butyl 4-[2-chloro-N-(methoxymethyl)nicotine amino]phenyl carbonate 

Relevant articles and documents

Synthesis method of N-BOC-ethylenediamine

The invention provides a synthesis method of N-BOC-ethylenediamine. The synthesis method of the N-BOC-ethylenediamine is characterized in that ethylenediamine and tert-butyl (p-nitrophenyl) carbonate (namely a self-made compound A) are subjected to a reac

MgBr 2 · OEt 2: A Lewis Acid Catalyst for the O - And N -Boc Protection of Phenols and Amines

MgBr2 · OEt2 efficiently catalyzes the O- and N-tert-butoxycarbonylation of functionalized phenols and amines. The presented procedure is operationally simple and done under solvent-free conditions. GRAPHICAL ABSTRACT.

Mixed metal MgO-ZrO2 nanoparticle-catalyzed O-tert-Boc protection of alcohols and phenols under solvent-free conditions

An environmentally benign method for O-tert-Boc protection of alcohols and phenols catalyzed by MgO-ZrO2 nanoparticles under solvent-free conditions is described. A variety of phenols, alcohols (aliphatic and aromatic) were converted to corresponding O-tert-Boc products in good to excellent yield (50-95%). The present protocol is expedient, simple, and efficient under solvent-free conditions. The MgO-ZrO2 Nps are easily prepared from inexpensive precursors, and are reusable, recyclable and chemoselective. Copyright 2012 John Wiley & Sons, Ltd. Copyright