13307-56-7

Basic information

• Product Name: Benzene, 1,1'-[ethylidenebis(thio)]bis-
• CAS NO: 13307-56-7
• Molecular Formula: C14H14S2
• Molecular Weight: 246.397
• Mol File: 13307-56-7.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-[ethylidenebis(thio)]bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[ethylidenebis(thio)]bis-(13307-56-7)
• EPA Substance Registry System: Benzene, 1,1'-[ethylidenebis(thio)]bis-(13307-56-7)

Safety Data

• Hazardous Substances Data: 13307-56-7(Hazardous Substances Data)

Upstream product

• 51207-25-1 ethylphenylsulfoxide 
• 108-98-5 thiophenol 
• 13557-24-9 1-chloroethyl phenyl sulfide 
• 108-05-4 vinyl acetate 
• 13307-76-1 [bis(phenylthio)methyl]lithium 
• 69190-58-5 (bis-phenylsulfanyl-methyl)-boronic acid 
• 36127-92-1 <(metoxycarbonyl)(phenylsulfinyl)methylene>triphenylphosphorane 
• 3561-67-9 bis(phenylthio)methane 
• 74-88-4 methyl iodide 
• 109-92-2 ethyl vinyl ether 
• 1822-73-7 phenylthioethylene 
• 75-34-3 1,1-dichloroethane 
• 69190-60-9 2-(bis-phenylsulfanyl-methyl)-[1,3,2]dioxaborinane 
• 67091-27-4 diphenyl-phosphinodithious acid methanediyl ester 

Downstream Products

• 77815-60-2 2,2-bis(phenylsulfanyl)hexane 
• 71221-34-6 2,2-Bis-(phenylthio)-hexan-3-ol 
• 77815-59-9 2,2-bis(phenylthio)pentane 
• 77815-62-4 2,2-bis(phenylthio)pent-4-ene 
• 33419-26-0 1,1-bis-benzenesulfonyl-ethane 
• 13023-53-5 3-phenylsulfanyl-butan-2-one 
• 66757-93-5 C₂₁H₁₈S₂ 
• 71221-35-7 2,2-Bis-(phenylthio)-hexan-3-on 
• 66080-38-4 2-(Phenylthio)hexan-3-one 
• 71221-45-9 2-Ethyl-2-phenylthiopentan-3-on 
• 28403-86-3 1-phenyl-2-(phenylthio)propan-1-one 
• 27872-70-4 2-(phenylthio)-3-pentanone 
• 16158-83-1 phenyl (1E)-1-phenylprop-1-en-2-yl sulfide 
• 16158-83-1 (Z)-β-phenylthio-β-methylstyrene 

Relevant articles and documents

Catalyst-dependent selective synthesis of O/S- and S/S-acetals from enol ethers

Enol ethers are reacted with mercaptanes to give the corresponding O/S- or S/S-acetals in medium to high yield. Either product can be formed selectively depending on the acid catalyst and the reaction time applied.

-

-

Synthesis of dithioacetals and oxathioacetals with chiral auxiliaries

One-pot synthesis of dithioacetals as well as an efficient method for oxathioacetal is reported. Additionally, some chiral auxiliaries were used to synthesize enantiomerically pure dithioacetals and oxathioacetals.

Aggregative activation and carbanion chemistry: Complex base deprotonation and directed functionalisation of dithioacetals

Bis(phenylthio)methane and [1,3]-dithiane were efficiently deprotonated by the NaNH2-Et(OCH2CH2)2-ONa complex base. A marked behaviour difference was observed between the sodium carbanion of [1,3]-dithiane and the corresponding lithio-derivative. A 'radicaloid' mechanism is proposed to explain the results observed.