13423-60-4

Basic information

• Product Name: 1H-1,2,4-Triazole,1-phenyl-(6CI,7CI,8CI,9CI)
• Synonyms: 1H-1,2,4-Triazole,1-phenyl-(6CI,7CI,8CI,9CI);1-Phenyl-1H-1,2,4-triazole
• CAS NO: 13423-60-4
• Molecular Formula: C₈H₇N₃
• Molecular Weight: 145.16
• Product Categories: TRIAZOLE
• Mol File: 13423-60-4.mol
• Article Data: 54

Chemical Properties

• Melting Point: 47 °C
• Boiling Point: 292.3°Cat760mmHg
• Flash Point: 130.6°C
• Appearance: /
• Density: 1.16g/cm³
• Vapor Pressure: 0.00184mmHg at 25°C
• Refractive Index: 1.632
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 2.32±0.10(Predicted)
• CAS DataBase Reference: 1H-1,2,4-Triazole,1-phenyl-(6CI,7CI,8CI,9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-1,2,4-Triazole,1-phenyl-(6CI,7CI,8CI,9CI)(13423-60-4)
• EPA Substance Registry System: 1H-1,2,4-Triazole,1-phenyl-(6CI,7CI,8CI,9CI)(13423-60-4)

Safety Data

• Hazardous Substances Data: 13423-60-4(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 21, p. 1037, 1956 DOI: 10.1021/jo01115a610

InChI:InChI=1/C8H7N3/c1-2-4-8(5-3-1)11-7-9-6-10-11/h1-7H

Upstream product

• 77287-34-4 formamide 
• 100-63-0 phenylhydrazine 
• 622-84-4 2-formyl-1-phenylhydrazine 
• 59-88-1 phenylhydrazine hydrochloride 
• 289-96-3 1,2,3-triazine 
• 288-88-0 1,2,4-Triazole 
• 591-50-4 iodobenzene 
• 2996-92-1 phenyl trimethylsiloxane 
• 290-87-9 1,3,5-Triazine 
• 62-53-3 aniline 
• 696-62-8 para-iodoanisole 
• 31709-15-6 N-(1-phenyl-1H-1,2,4-triazol-3-yl)benzamide 
• 98-80-6 phenylboronic acid 
• 58131-64-9 methyl 2-chloro-2-(2-phenylhydrazono)acetate 

Downstream Products

• 100820-35-7 Phenyl-(2-phenyl-2H-[1,2,4]triazol-3-yl)-methanone 
• 114532-37-5 anhydro-2,7-diphenyl-1-hydroxy-3-oxopyrrolo<1,2-d>-1,2,4-triazolium hydroxide 
• 100820-32-4 5-thiomethyl-1-phenyl-1,2,4-triazole 
• 100820-37-9 1-phenyl-1,2,4,-triazole-5-carboxylic acid lithium salt 
• 100820-36-8 5-ethyl-1-phenyl-1H-1,2,4-triazole 
• 100820-34-6 5-Methoxymethyl-1-phenyl-1H-[1,2,4]triazole 
• 83096-18-8 1-phenyl-1,2,4-triazolium-4-dicyanomethylide 
• 100820-33-5 1-Phenyl-5-phenylsulfanyl-1H-[1,2,4]triazole 
• 21434-18-4 1,2-dihydro-2-phenyl-3H-1,2,4-triazole-3-thione 
• 21434-15-1 5-bromo-1-phenyl-1H-1,2,4-triazole 
• 1193686-46-2 2,2-dimethyl-1-(1-phenyl-1H-1,2,4-triazol-5-yl)propan-1-ol 
• 1206483-05-7 1-phenyl-5-phenylethynyl-1H-[1,2,4]triazole 
• 1176199-53-3 1-phenyl-4-undecyl-1H-1,2,4-triazolium bromide 
• 1176199-58-8 1-phenyl-4-ethyl-1H-1,2,4-triazolium bis(trifluoromethylsulfonyl)imide 

Relevant articles and documents

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Deprotometalation-iodolysis and computed CH acidity of 1,2,3- and 1,2,4-triazoles. Application to the synthesis of resveratrol analogues

1-Aryl- and 2-aryl-1,2,3-triazoles were synthesized by N-arylation of the corresponding azoles using aryl iodides. The deprotometalations of 1-phenyl-1,2,3-triazole and -1,2,4-triazole were performed using a 2,2,6,6-tetramethylpiperidino-based mixed lithi

A novel two-dimensional metal-organic framework as a recyclable heterogeneous catalyst for the dehydrogenative oxidation of alcohol and theN-arylation of azole compounds

A novel metal-organic framework (MOF) with two-dimensional (2D) crystal structure was developed using Cu(NO3)2·3H2O and 2,2′,5,5′-tetramethoxy-[1,1′-biphenyl]-4,4′-dicarboxylic acid. Further, its structure was characterized using infrared spectroscopy, thermogravimetry, X-ray diffraction, and X-ray crystallography. The activated Cu-MOF was used to catalyze the dehydrogenative oxidation of alcohol andN-arylation of azole compounds. Furthermore, it could be easily recovered and reused.

Facile One-Pot Synthesis of Methyl 1-Aryl-1H-1,2,4-triazole-3-carboxylates from Nitrilimines with Vilsmeier Reagent

Two convenient and effective one-pot methods have been developed to synthesize methyl 1-aryl-1H-1,2,4-triazole1–3-carboxylates by using hydrazonoyl hydrochlorides (nitrilimines) with Vilsmeier reagent. The first, a direct one-pot method, involved the reac