13456-78-5Relevant articles and documents
Aqueous-mediated N-alkylation of amines
Singh, Chingakham B.,Kavala, Veerababurao,Samal, Akshaya K.,Patel, Bhisma K.
, p. 1369 - 1377 (2008/09/17)
Direct N-alkylation of primary amines to secondary/tertiary amines and of secondary amines to tertiary amines has been achieved in excellent yields by employing alkyl, benzylic and allylic halides in the presence of NaHCO 3 in an aqueous medium at an elevated temperature. Amines of different stereoelectronic nature react with ease with different halides. The selective formation of secondary amines and the formation of three different substituted tertiary amines are some of the interesting features of this methodology. Reaction in an aqueous medium, operationally convenient conditions, excellent yields and innocuous byproducts, and the absence of transition-metal catalysts, expensive bases, solid supports and the formation of undesired quaternary ammonium salts makes this method a green chemical process. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
ESR and ENDOR investigations on various Wurster's radical cations in solution. Experimental results, theoretical ab initio, and DFT calculations
Grampp, Guenter,Kelterer, Anne-Marie,Landgraf, Stephan,Sacher, Michael,Niethammer, Dominique,Telo, Joao P.,Dias, Rui M. B.,Vieira, Abel J. S. C.
, p. 519 - 536 (2007/10/03)
ESR and ENDOR spectra are reported of several symmetrical substituted N,N,N′,N′-tetraalkyl-p-phenylenediamine radical cations in solution. Different N,N′-alkyl substituted paraphenylenediamines, like the ethyl, n-propyl, and iso-propyl derivative are compared with the parent N,N,N′,N′-tetramethyl-p-phenylenediamine (Wurster's Blue Cation). N,N,N′,N′-Tetrabenzyl-p-phenylenediamine, 1,4-dipyrrolidinylbenzene, and N,N′-bis[4-(dimethylamino)phenyl]piperazine are additionally investigated. Experimental and calculated hyperfine coupling constants are compared. Characteristic UV-VIS data and redox potentials in acetonitrile are reported, together with the syntheses of the compounds. Springer-Verlag 2005.