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N,N,N',N'-TETRABENZYL-P-PHENYLENEDIAMINE, also known as TBPD, is a chemical compound that serves as a polymerization inhibitor and antioxidant. It is a diamine with four benzyl groups attached, exhibiting a white to light brown solid form at room temperature. TBPD is soluble in organic solvents and is recognized for its ability to scavenge free radicals and stabilize polymer chains, which extends the shelf life and enhances the performance of materials in which it is used.

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  • 13456-78-5 Structure
  • Basic information

    1. Product Name: N,N,N',N'-TETRABENZYL-P-PHENYLENEDIAMINE
    2. Synonyms: N,N,N',N'-TETRABENZYL-P-PHENYLENEDIAMINE;LABOTEST-BB LT00454976;N1,N1,N4,N4-Tetrabenzylbenzene-1,4-diamine
    3. CAS NO:13456-78-5
    4. Molecular Formula: C34H32N2
    5. Molecular Weight: 468.63
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 13456-78-5.mol
  • Chemical Properties

    1. Melting Point: 149-152°C
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: N,N,N',N'-TETRABENZYL-P-PHENYLENEDIAMINE(CAS DataBase Reference)
    10. NIST Chemistry Reference: N,N,N',N'-TETRABENZYL-P-PHENYLENEDIAMINE(13456-78-5)
    11. EPA Substance Registry System: N,N,N',N'-TETRABENZYL-P-PHENYLENEDIAMINE(13456-78-5)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: 22-24/25
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 13456-78-5(Hazardous Substances Data)

13456-78-5 Usage

Uses

Used in Rubber and Plastics Industry:
N,N,N',N'-TETRABENZYL-P-PHENYLENEDIAMINE is used as a polymerization inhibitor and antioxidant for preventing premature polymerization and degradation in the production of rubbers, plastics, and adhesives. It contributes to the stabilization of polymer chains, thereby improving the durability and performance of these materials.
Used in Lubricants and Fuels Production:
N,N,N',N'-TETRABENZYL-P-PHENYLENEDIAMINE is used as a stabilizer in the production of lubricants and fuels to enhance their stability and performance over time.
Used in Pharmaceutical and Agrochemical Synthesis:
N,N,N',N'-TETRABENZYL-P-PHENYLENEDIAMINE is utilized as a chemical intermediate in the synthesis of pharmaceuticals and agrochemicals, playing a crucial role in the development of various medicinal and agricultural products.
It is important to handle N,N,N',N'-TETRABENZYL-P-PHENYLENEDIAMINE with care due to its classification as a hazardous substance, which poses potential health and environmental risks. Proper safety measures should be taken during its use and disposal to mitigate any adverse effects.

Check Digit Verification of cas no

The CAS Registry Mumber 13456-78-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,4,5 and 6 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 13456-78:
(7*1)+(6*3)+(5*4)+(4*5)+(3*6)+(2*7)+(1*8)=105
105 % 10 = 5
So 13456-78-5 is a valid CAS Registry Number.

13456-78-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name N,N,N',N'-TETRABENZYL-P-PHENYLENEDIAMINE

1.2 Other means of identification

Product number -
Other names N,N,N',N'-Tetrabenzyl-1,4-Benzenediamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13456-78-5 SDS

13456-78-5Downstream Products

13456-78-5Relevant articles and documents

Aqueous-mediated N-alkylation of amines

Singh, Chingakham B.,Kavala, Veerababurao,Samal, Akshaya K.,Patel, Bhisma K.

, p. 1369 - 1377 (2008/09/17)

Direct N-alkylation of primary amines to secondary/tertiary amines and of secondary amines to tertiary amines has been achieved in excellent yields by employing alkyl, benzylic and allylic halides in the presence of NaHCO 3 in an aqueous medium at an elevated temperature. Amines of different stereoelectronic nature react with ease with different halides. The selective formation of secondary amines and the formation of three different substituted tertiary amines are some of the interesting features of this methodology. Reaction in an aqueous medium, operationally convenient conditions, excellent yields and innocuous byproducts, and the absence of transition-metal catalysts, expensive bases, solid supports and the formation of undesired quaternary ammonium salts makes this method a green chemical process. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

ESR and ENDOR investigations on various Wurster's radical cations in solution. Experimental results, theoretical ab initio, and DFT calculations

Grampp, Guenter,Kelterer, Anne-Marie,Landgraf, Stephan,Sacher, Michael,Niethammer, Dominique,Telo, Joao P.,Dias, Rui M. B.,Vieira, Abel J. S. C.

, p. 519 - 536 (2007/10/03)

ESR and ENDOR spectra are reported of several symmetrical substituted N,N,N′,N′-tetraalkyl-p-phenylenediamine radical cations in solution. Different N,N′-alkyl substituted paraphenylenediamines, like the ethyl, n-propyl, and iso-propyl derivative are compared with the parent N,N,N′,N′-tetramethyl-p-phenylenediamine (Wurster's Blue Cation). N,N,N′,N′-Tetrabenzyl-p-phenylenediamine, 1,4-dipyrrolidinylbenzene, and N,N′-bis[4-(dimethylamino)phenyl]piperazine are additionally investigated. Experimental and calculated hyperfine coupling constants are compared. Characteristic UV-VIS data and redox potentials in acetonitrile are reported, together with the syntheses of the compounds. Springer-Verlag 2005.

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