134932-19-7Relevant academic research and scientific papers
Enzyme Assisted Synthesis of Enantiomerically Pure myo-Inositol Derivatives - Chiral Building Blocks for Inositol Polyphosphates
Andersch, P.,Schneider, M. P.
, p. 2135 - 2138 (2007/10/02)
Using a short and facile synthetic protocol involving highly selective, regio- and enentioselective enzymatic esterifications as key reaction steps, readily available myo-inositol is converted into optically pure 1D-1-O-butyryl-4,6-O-dibenzoyl-myo-inositol (-) - 5, a selectively protected central intermediate for the preparation of numerous inositol phosphates.
A Chiral Synthesis of D-myo-Inositol 1-Phosphate Starting from L-Quebrachitol
Akiyama, Takahiko,Takechi, Naoto,Ozaki, Shoichiro,Shiota, Kenji
, p. 366 - 372 (2007/10/02)
A naturally occurring optically active cyclitol, L-quebrachitol (1L-2-O-methyl-chiro-inositol), was stereoselectively transformed into myo-inositol derivatives via an oxidation-reduction process.The methyl ether was cleaved chemoselectively with AlCl3NaI
Chiral synthesis of D-Myo-inositol 1-phosphate starting from L-querbrachitol
Akiyama,Takechi,Ozaki
, p. 1433 - 1434 (2007/10/02)
D-Myo-inositol 1-phosphate was synthesized from L-quebrachitol via stereoselective inversion of a 3-hydroxyl group and chemoselective demethylation.
SYNTHESIS OF 1D- AND 1L-4-O-BENZYL-myo-INOSITOL, 1D-4-O-α-L-FUCOPYRANOSYL-myo-INOSITOL (IDENTICAL TO A NATURAL GLYCOSIDE), AND 1L-4-O-α-L-FUCOPYRANOSYL-myo-INOSITOL
Garegg, Per J.,Lindberg, Bengt,Kvarnstroem, Ingemar,Svensson, Stefan C. T.
, p. 209 - 216 (2007/10/02)
The α-L-fucopyranosyl-myo-inositol isolated from human urine has been proved to be the 1D-4-O-myo-inositol derivative by unambiguous syntheses of this substance and of the diastereomeric 1L-4-O-myo-inositol derivative.The chiral penta-O-benzoyl-myo-inosit
