135-59-1

Basic information

• Product Name: THIONIN
• Synonyms: THIONIN;THIONINE CHLORIDE;CI 52000;CI NO 5200;CI NO 52000;LAUTHS VIOLET;LAUTH'S VIOLET;3-imino-3H-phenothiazin-7-amine
• CAS NO: 135-59-1
• Molecular Formula: C₁₂H₉N₃S
• Molecular Weight: 263.75
• EINECS: 205-204-5
• Product Categories: Sulphur Derivatives
• Mol File: 135-59-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 416.3 °C at 760 mmHg
• Flash Point: 205.6 °C
• Appearance: /
• Density: 1.48 g/cm³
• Vapor Pressure: 3.85E-07mmHg at 25°C
• Refractive Index: 1.791
• CAS DataBase Reference: THIONIN(CAS DataBase Reference)
• NIST Chemistry Reference: THIONIN(135-59-1)
• EPA Substance Registry System: THIONIN(135-59-1)

Safety Data

• Hazardous Substances Data: 135-59-1(Hazardous Substances Data)

Usage

Description

THIONIN is an organic compound that is commonly used as a dye and has various applications across different industries due to its unique properties.

Uses

Used in General Nuclear Staining:
THIONIN is used as a staining agent for general nuclear staining, allowing for the visualization and examination of cell nuclei in various biological samples.
Used in Bacterial Counting in Milk:
In the dairy industry, THIONIN is utilized as a dye for counting bacteria in milk, helping to ensure the quality and safety of milk products.
Used as an Antioxidant for Linseed Oil:
THIONIN serves as an antioxidant in the production of linseed oil, preventing the oxidation and spoilage of the oil, thus extending its shelf life and maintaining its quality.
Used as a Catalyst in Chemical Reactions:
THIONIN has been employed as a catalyst in the condensation of 1,3-butadienyl ethyl ether with maleic anhydride, a process that is important in the synthesis of various chemical compounds.

InChI:InChI=1/C12H9N3S/c13-7-1-3-9-11(5-7)16-12-6-8(14)2-4-10(12)15-9/h1-6,13H,14H2

Upstream product

• 6138-09-6 leucothionine 
• 129-00-0 pyrene 
• 78338-22-4 thionine 
• 91-16-7 1,2-dimethoxybenzene 
• 106-50-3 1,4-phenylenediamine 
• 632-51-9 1,1,2,2-tetraphenylethylene 
• 122-39-4 diphenylamine 
• 781-43-1 9,10-dimethylanthracene 
• 779-02-2 9-methylanthracene 
• 5283-05-6 azure A 
• 7664-41-7 ammonia 
• 7732-18-5 water 
• 302-72-7 rac-Ala-OH 

Downstream Products

• 109162-68-7 3,7-diamino-2,4,6,8-tetrachloro-phenothiazinylium; chloride 
• 4773-89-1 1,4-cyclohexadiene-1,2-dicarboxylic anhydride 

Related news

Is there a difference in metal ion-based inhibition between members of THIONIN (cas 135-59-1) family: Molecular dynamics simulation study09/29/2019

Thionins have a considerable potential as antimicrobial compounds although their application may be restricted by metal ion-based inhibition of membrane permeabilizing activity. We previously reported the properties associated with the proposed mechanism of metal ion-based inhibition of β-purot...detailed

Langmuir Aggregation of THIONIN (cas 135-59-1) on Sodium Dodecyl Sulfate and Its Application10/01/2019

The microphase adsorption–spectral correction (MPASC) technique was applied to the interaction of thioin (TN) with sodium dodecyl sulfate (SDS) at pH 4.56. The synergism mechanism of SDS in solution was analyzed and discussed. The great electrostatic aggregation of TN on SDS obeys Langmuir mono...detailed

Relevant articles and documents

NMR analysis of Nile Blue (C. I. Basic Blue 12) and Thionine (C. I. 52000) in solution

The dyes Nile Blue (C. I. Basic Blue 12) and Thionine (C. I. 52000) were examined in both ionic and neutral forms in different solvents using NMR and UV-visible spectroscopy to firmly establish the structures of the molecules and to assess the nature and extent of their aggregation. 1H and 13C NMR assignments and chemical shift data were used, together with nuclear Overhauser effect information, to propose a self-assembly structure. These data were supplemented with variable temperature, dilution and diffusion-based experimental results using 1H NMR spectroscopy thereby enabling extended aggregate structures to be assessed in terms of the relative strength of self-association and the extent to which extended aggregates could form.

The Relation between Radical Yield and Free Enthalpy Change for Triplet State Electron Transfer Reactions in Acetonitrile

The electron transfer reaction from aromatic compounds without heavy atom substituents to triplet thionine has been studied in acetonitrile by an emission-absorption flash technique.The free radical yield ΦR was slightly less than unity in the range of the free enthalpy change of reaction, ΔG = -0.46 ca. - 0.16 eV, but it was close to unity in the other range of ΔG.This dependence of ΦR on ΔG is different from that in the excited singlet state reported by Iwa et al. - Keywords: Electron transfer reaction / Triplet state / Thione