Journal of Organic Chemistry p. 6256 - 6257 (1991)
Update date:2022-09-26
Topics:
Oppolzer, Wolfgang
DeVita, Robert J.
The Pd(0)-catalyzed polycyclizations 1 -> 3 + 4, 5 -> 9 and 6 -> 10 are described.The stereospecifity of these transformations is ascribed to an intramolecular suprafacial "palladium-ene" process followed by one to two "Heck-insertions" proceeding with re
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