1367368-61-3Relevant academic research and scientific papers
Direct Synthesis of α-Allenols from TMS-Protected Alkynes and Aldehydes Mediated by Tetrabutylammonium Fluoride
Huang, Xiaojun,Bugarin, Alejandro
supporting information, p. 12696 - 12700 (2016/08/30)
A unique chemoselective synthesis of α-allenic alcohols is presented. Tetrabutylammonium fluoride (TBAF) mediated this transformation under mild reaction conditions. A range of functional groups is well-tolerated in this reaction, while affording adducts
C(sp)-C(sp3) bond formation through cu-catalyzed cross-coupling of N -tosylhydrazones and trialkylsilylethynes
Ye, Fei,Ma, Xiaoshen,Xiao, Qing,Li, Huan,Zhang, Yan,Wang, Jianbo
supporting information; experimental part, p. 5742 - 5745 (2012/05/07)
Copper-catalyzed cross-coupling of N-tosylhydrazones with trialkylsilylethynes leads to the formation of C(sp)-C(sp3) bonds. Cu carbene migratory insertion is proposed to play the key role in this transformation.
