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Usage

Uses

Used in Perfumery:
FEMA 3759 is used as a fragrance ingredient for its pungent, herbaceous-green, bold-like camphoraceous, piney, terpene-like, and slightly cineol-like odor. It adds a fresh and natural scent to perfumes, contributing to their overall appeal.
Used in Flavor Industry:
FEMA 3759 is used as a flavoring agent for its unique and complex aroma. It can be used to enhance the taste and smell of various food and beverage products, providing a refreshing and natural flavor profile.
Used in Aromatherapy:
FEMA 3759 is used as an essential oil in aromatherapy for its invigorating and refreshing properties. Its pungent and herbaceous scent can help promote relaxation, reduce stress, and improve overall well-being.
Used in Cosmetics:
FEMA 3759 is used as an additive in the cosmetics industry for its pleasant and natural scent. It can be incorporated into various cosmetic products, such as lotions, creams, and soaps, to provide a refreshing and uplifting experience for users.
Used in the Pharmaceutical Industry:
FEMA 3759 is used as a component in the development of pharmaceutical products due to its unique chemical properties. It can be used in the formulation of medications, particularly those targeting respiratory and musculoskeletal issues, due to its refreshing and invigorating properties.

InChI:InChI=1/C10H16O/c1-5-10(4)7-6-9(11-10)8(2)3/h5,9H,1-2,6-7H2,3-4H3

Upstream product

• 29414-55-9 6,7-epoxymyrcene 
• 67-56-1 methanol 
• 78-70-6 3,7-dimethylocta-1,6-dien-3-ol 
• 74514-23-1 6-chloro-3,7-dimethylocta-1,7-dien-3-ol 
• 97277-68-4 xanthate of 1-(5-ethenyl-5-methyl-2-tetrahydrofuranyl)-1-methylethanol 
• 71328-53-5 5-(1'-bromo-1'-methyl) ethyl-2-methyl-2-vinyltetrahydrofurane 
• 118989-24-5 5-ethenyl-5-methyl-2-<1-methyl-1-(phenylseleno)ethyl>tetrahydrofuran 
• 60047-17-8 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran 
• 29171-20-8 3,7-dimethyloct-6-en-1-yn-3-ol 
• 74026-67-8 5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-1-yn-3-ol 
• 97277-67-3 1-(5-ethynyl-5-methyl-2-tetrahydrofuranyl)-1-methylethanol 

Downstream Products

• 19822-67-4 2,2,5-trimethylcyclohept-4-en-1-one 
• 67304-14-7 2-methyl-2-vinyl-5-isopropylidenetetrahydrofuran 

Relevant academic research and scientific papers

CHLORATION ALLYLIQUE D'OLEFINES DE TYPE ISOPRENIQUE A L'AIDE DU CHLORURE DE SULFURYLE

Sulfuryl chloride is a convenient reagent for the allylic chlorination of olefins bearing an isopropenyl or isopropylidenyl moiety.The substitution occurs with good yields and with allylic rearrangement, giving in most cases a secondary chloride.

Simple synthesis of karahanaenone

Karahanaenone 1 has been prepared from linalool 3. Linalool 3 is cyclized to the corresponding tetrahydrofuran-type cyclic ethers 4a-c on treatment with PhSeCl, N-bromosuccinimide, and 3-chloroperbenzoic acid, respectively. 4a-c on further treatment with various reagents, provide allylic cyclic ether 6 which is converted to 1 via 2.

THE STRUCTURAL DIRECTION OF THE ELECTROCHEMICAL OXIDATION OF LINALOOL

The electrochemical oxidation of linalool in methanol containing alkaline electrolytes leads to direct anodic oxidation of the substrate at the C6=C7 bond.Heterocyclization and molecular rearrangements take place to a significant degree in addition to methoxylation.Acetal protection of the hydroxyl group prevents the formation of the heterocyclization products and thereby increases the selectivity of the reaction with respect to the methoxylation products.

Synthesis of Karahanaenone

Karahanaenone (1) has been prepared from dehydrolinalyl acetate.Electrochemical epoxidation of dehydrolinalyl acetate provided the corresponding epoxide 6a (75percent) which was converted to keto acetate 7a (82percent) by an electrogenerated acid-catalyzed rearrangement.Hydrogenation followed by alkaline hydrolysis gave 6-hydroxy-2,6-dimethyl-7-octen-3-one (7c) (86percent), which was subjected to thermal dehydration at 200 deg C to give 1 (85percent) via Claisen type rearrangement of the intermediate 2-methyl-2-ethenyl-5-propylidenetetrahydrofuran (2).An alternative route to 1 via thermolysis of the xanthate of 1-(5-ethenyl-5-methyl-2-tetrahydrofuranyl)-1-methylethanol (10b) is also described.

Acid-catalyzed Rearrangements of Linalool Oxide

Reaction of linalool oxide (1) with acids leads to a variety of dehydration products which are shown to be aliphatic dienones and /or monocyclic enones.A mechanism is proposed to account for the generation of all these compounds.

Heterocyclic compound as odor- and flavor-modifying agent

New heterocyclic compound useful as odor-modifying agent for manufacturing perfumes, perfumed products, natural or synthetic essential oils, and as flavor-modifying agent for the manufacture of artificial flavors or for flavoring foodstuffs, animal feeds, beverages, pharmaceutical preparations and tobacco products. Process for preparing said heterocyclic compound.