60047-17-8

Basic information

• Product Name: Linalool oxide
• Synonyms: linalooloxide,mixtureofisomers;Linolooloxide;2-(tetrahydro-5-methyl-5-vinyl-2-furyl)propan-2-ol;1,5-Dimethyl-1-vinyl-4-hexenol;Linalol oxide;2-Methyl-2-Vinyl-5-(a-hydroxy-isopropyl) -tetrahydrofunan;linalooloxide,epoxydihydrolinalool;LINALOOL OXIDE(RG)
• CAS NO: 60047-17-8
• Molecular Formula: C₁₀H₁₈O₂
• Molecular Weight: 170.25
• EINECS: 262-038-6
• Product Categories: Biochemistry;Terpenes;Terpenes (Others)
• Mol File: 60047-17-8.mol
• Article Data: 31

Chemical Properties

• Boiling Point: 188°C
• Flash Point: 63°C
• Appearance: /
• Density: 0.945 g/mL at 20 °C(lit.)
• Vapor Pressure: 1.58-2.1hPa at 20-25℃
• Refractive Index: n20/D 1.452
• PKA: 14.57±0.29(Predicted)
• BRN: 117527
• CAS DataBase Reference: Linalool oxide(CAS DataBase Reference)
• NIST Chemistry Reference: Linalool oxide(60047-17-8)
• EPA Substance Registry System: Linalool oxide(60047-17-8)

Safety Data

• Hazard Codes: C
• Statements: 22-34
• Safety Statements: 23-24/25-45-36/37/39-26
• RIDADR: UN 1760 8 / PGIII
• WGK Germany: 2
• RTECS: OI7782000
• F: 10
• Hazardous Substances Data: 60047-17-8(Hazardous Substances Data)

Usage

General Description

Linalool oxide is a monoterpenoid compound, commonly found in some species of the aromatic plants. It can be obtained from linalool either by oxidation or via biotransfomation using the fungus Aspergillus niger. It is always present as a mixture of both cis and trans forms.

InChI:InChI=1/C10H18O2/c1-5-10(4)7-6-8(12-10)9(2,3)11/h5,8,11H,1,6-7H2,2-4H3

Synthetic route

1-(5-ethynyl-5-methyl-2-tetrahydrofuranyl)-1-methylethanol (97277-67-3) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
With quinoline; hydrogen; Pd-BaSO4 In methanol Ambient temperature;	92%

3,7-dimethylocta-1,6-dien-3-ol (78-70-6) → 6,7-epoxylinalool (15249-35-1) + 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
With pyridine; pyridine-3-carbonitrile; dihydrogen peroxide; methyltrioxorhenium(VII) In dichloromethane; water at -0.15℃; for 1.7h; Yields of byproduct given;	A 82% B n/a

5,6-epoxy-6-methyl-2-heptanone (16262-93-4) + vinyl magnesium bromide (1826-67-1) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
In tetrahydrofuran for 12h; Ambient temperature;	75%

3,7-dimethylocta-1,6-dien-3-ol (78-70-6) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
With maleic anhydride; urea-hydrogen peroxide complex In dichloromethane at 0℃; for 5h;	75%
With 3-chloro-benzenecarboperoxoic acid In chloroform at 0℃; for 8h;	72%
With Beauveria sulfurescens ATCC7159 In various solvent(s) for 16h;

C17H26O5S → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
With potassium tert-butylate; tert-butyl alcohol at 70 - 80℃; for 6h;	72.91%

2-[5-(1-Iodo-ethyl)-5-methyl-tetrahydro-furan-2-yl]-propan-2-ol → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
With potassium tert-butylate In N,N-dimethyl-formamide at 25℃;	70%

(2E)-3-methyl-5-{(4R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl}-2-pentene-1-ol (119906-63-7) + trifluoromethylsulfonic anhydride (358-23-6) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) + C14H23F3O5S

Conditions	Yield
at -78℃;	A n/a B 43%

trifluoromethylsulfonic anhydride (358-23-6) + (4'S,2E)-3-methyl-5-(2',2',5',5'-tetramethyl-1',3'-dioxolan-4'-yl)-2-penten-1-ol (61262-97-3) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) + C14H23F3O5S

Conditions	Yield
at -78℃;	A n/a B 43%

peracetic acid (79-21-0) + linalool (126-91-0) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

monoperoxyphthalic acid (2311-91-3) + linalool (126-91-0) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Acetic acid 1-[5-(1-iodo-ethyl)-5-methyl-tetrahydro-furan-2-yl]-1-methyl-ethyl ester → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
With potassium tert-butylate; hydroxide 1) DMF, 25 deg C; Yield given. Multistep reaction;

3,7-dimethylocta-1,6-dien-3-ol (78-70-6) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) + 3-hydroxy-2,2,6-trimethyl-6-vinyltetrahydropyran (14049-11-7)

Conditions	Yield
With cetylpyridinium peroxotungstophosphate; dihydrogen peroxide In chloroform; water for 1h; Ambient temperature;	A 48 % Chromat. B 22 % Chromat.
With tert.-butylhydroperoxide; Ti-MCM-41 zeolite In acetonitrile at 79.9℃; for 24h; Product distribution; var. of catalyst, time;	A 37.8 % Turnov. B 42.3 % Turnov.
With cetylpyridinium peroxotungstophosphate; dihydrogen peroxide In chloroform; water for 1h; Mechanism; Ambient temperature;	A 48 % Chromat. B 22 % Chromat.

oct-1-ene (111-66-0) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) + 1,2-Epoxyoctane (2984-50-1)

Conditions	Yield
With cetylpyridinium peroxotungstophosphate; dihydrogen peroxide In chloroform; tert-butyl alcohol at 60℃; for 8h;	A 48 % Chromat. B 76 % Chromat.

3,7-dimethylocta-1,6-dien-3-ol (78-70-6) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) + 3-hydroxy-2,2,6-trimethyl-6-vinyltetrahydropyran (14049-11-7) + Nerol (106-25-2)

Conditions	Yield
With titanium silicate; dihydrogen peroxide In methanol; water at 59.84℃; for 24h;

3,7-dimethylocta-1,6-dien-3-ol (78-70-6) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) + Nerol (106-25-2)

Conditions	Yield
With dihydrogen peroxide; aluminium In methanol; water at 59.84℃; for 31h;

3,7-dimethyloct-6-en-1-yn-3-ol (29171-20-8) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
Multi-step reaction with 3 steps 1: NaBr / acetonitrile; H2O / 9 h / Ambient temperature; electrolysis 2: NaOH / acetonitrile; H2O / 1 h / Ambient temperature 3: 92 percent / H2(g), quinoline / 5percent Pd/BaSO4 / methanol / Ambient temperature View Scheme

5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-1-yn-3-ol (74026-67-8) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
Multi-step reaction with 2 steps 1: NaOH / acetonitrile; H2O / 1 h / Ambient temperature 2: 92 percent / H2(g), quinoline / 5percent Pd/BaSO4 / methanol / Ambient temperature View Scheme

2,3-Dihydroxy-2,6-dimethyl-octen-(6) (78631-57-9) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
Multi-step reaction with 2 steps 1: I2, NaHCO3 / acetonitrile / 0 °C 2: 70 percent / KO-t-Bu / dimethylformamide / 25 °C View Scheme

Acetic acid (E)-2-benzyloxy-1,1,5-trimethyl-hept-5-enyl ester (78631-58-0) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
Multi-step reaction with 2 steps 1: I2 / acetonitrile / 0 °C 2: 1.) KO-t-Bu, 2.) OH(1-) / 1) DMF, 25 deg C View Scheme

3,7-dimethylocta-1,6-dien-3-ol (78-70-6) → 6,7-epoxylinalool (15249-35-1) + 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) + 3-hydroxy-2,2,6-trimethyl-6-vinyltetrahydropyran (14049-11-7)

Conditions	Yield
With [(n-C6H13)4N]3[PO4[WO(O2)2]4]; dihydrogen peroxide In water; acetonitrile at 80℃; for 5h; Catalytic behavior;

3,7-dimethylocta-1,6-dien-3-ol (78-70-6) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) + 3-hydroxy-2,2,6-trimethyl-6-vinyltetrahydropyran (14049-11-7) + epoxy-linalooloxide (861071-75-2)

Conditions	Yield
With 4C19H34N(1+)*HBW4O24(4-); dihydrogen peroxide In water; acetonitrile at 80℃; for 5h; Catalytic behavior;
With 7C16H36N(1+)*3H(1+)*2H2O*(Co2PW9O34)2(10-); dihydrogen peroxide In water; acetonitrile at 80℃; for 5h; Catalytic behavior; Reagent/catalyst; Temperature;

Essigsaeure-<(6S,2E)-6,7-dihydroxy-3,7-dimethyl-2-octen-1-yl>ester (61302-43-0) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
Multi-step reaction with 3 steps 1: toluene-4-sulfonic acid / methanol / 3 h / 20 °C 2: potassium carbonate / methanol / 24 h / 20 °C 3: -78 °C View Scheme
Multi-step reaction with 4 steps 1: toluene-4-sulfonic acid / methanol / 3 h / 20 °C 2: potassium carbonate / methanol / 24 h / 20 °C 3: -78 °C 4: Irradiation View Scheme
Multi-step reaction with 4 steps 1: toluene-4-sulfonic acid / methanol / 3 h / 20 °C 2: potassium carbonate / methanol / 24 h / 20 °C 3: phosphorus tribromide / diethyl ether / 0.33 h / -7 °C 4: Irradiation View Scheme

Essigsaeure-<(6S,2E)-6,7-isopropylidendioxy-3,7-dimethyl-2-octen-1-yl>ester (61262-98-4) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium carbonate / methanol / 24 h / 20 °C 2: -78 °C View Scheme
Multi-step reaction with 3 steps 1: potassium carbonate / methanol / 24 h / 20 °C 2: -78 °C 3: Irradiation View Scheme
Multi-step reaction with 3 steps 1: potassium carbonate / methanol / 24 h / 20 °C 2: phosphorus tribromide / diethyl ether / 0.33 h / -7 °C 3: Irradiation View Scheme

(2E)-3-methyl-5-{(4R)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl}-2-pentene-1-ol (119906-63-7) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
Multi-step reaction with 2 steps 1: phosphorus tribromide / diethyl ether / 0.33 h / -7 °C 2: Irradiation View Scheme
Multi-step reaction with 2 steps 1: -78 °C 2: Irradiation View Scheme

(4'S,2E)-3-methyl-5-(2',2',5',5'-tetramethyl-1',3'-dioxolan-4'-yl)-2-penten-1-ol (61262-97-3) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
Multi-step reaction with 2 steps 1: phosphorus tribromide / diethyl ether / 0.33 h / -7 °C 2: Irradiation View Scheme
Multi-step reaction with 2 steps 1: -78 °C 2: Irradiation View Scheme

(4'S,2E)-1-brom-3-methyl-5-(2',2',5',5'-tetramethyl-1',3'-dioxolan-4'-yl)-2-penten (116660-94-7) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
Irradiation;

C14H23F3O5S → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
Irradiation;

C14H23F3O5S → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
Irradiation;

essigsaeure-<(E,R)-6,7-dihydroxy-3,7-dimethyl-2-octenyl>ester (86561-84-4) → 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8)

Conditions	Yield
Multi-step reaction with 3 steps 1: toluene-4-sulfonic acid / methanol / 3 h / 20 °C 2: potassium carbonate / methanol / 24 h / 20 °C 3: -78 °C View Scheme
Multi-step reaction with 4 steps 1: toluene-4-sulfonic acid / methanol / 3 h / 20 °C 2: potassium carbonate / methanol / 24 h / 20 °C 3: -78 °C 4: Irradiation View Scheme
Multi-step reaction with 4 steps 1: toluene-4-sulfonic acid / methanol / 3 h / 20 °C 2: potassium carbonate / methanol / 24 h / 20 °C 3: phosphorus tribromide / diethyl ether / 0.33 h / -7 °C 4: Irradiation View Scheme

2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) → methyl-2 ethyl-2 (methyl-1 hydroxy-1 ethyl)-5 tetrahydrofuranne

Conditions	Yield
With triethylsilane; 1% Pd on activated carbon In water at 20℃; for 12h; Reagent/catalyst; Green chemistry; chemoselective reaction;	99%
With hydrogen; palladium 10% on activated carbon In methanol at 30℃;	88%

2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) → 5-methyl-5-vinyl-dihydro-furan-2-one (1073-11-6)

Conditions	Yield
With 3 A molecular sieve; pyridinium chlorochromate In dichloromethane for 3h; Heating;	73%
With 3 A molecular sieve; pyridinium chlorochromate In dichloromethane for 4h; Heating;	73%

2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) + acetyl chloride (75-36-5) → acetic acid 1-methyl-1-(5-methyl-5-vinyl-tetrahydro-furan-2-yl)-ethyl ester

Conditions	Yield
With pyridine; dmap In dichloromethane at 0 - 20℃; Acetylation;	53%

2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) + ethyl vinyl ether (109-92-2) → 5-(2-(1-ethoxyethoxy)propan-2-yl)-2-methyl-2-vinyltetrahydrofuran

Conditions	Yield
With toluene-4-sulfonic acid In diethyl ether at 5 - 20℃; for 12.5h;	37%

monomethyl oxalyl chloride (5781-53-3) + 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) → C13H20O5 + C13H20O5

Conditions	Yield
With pyridine In diethyl ether at 22℃; for 16h; Inert atmosphere;	A 30% B 32%

2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) → 2,6-dimethyl-octa-4,6-dien-3-one (91056-18-7)

Conditions	Yield
With hydrogen cation

carbon disulfide (75-15-0) + 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) → C11H17O2S2(1-)*Na(1+)

Conditions	Yield
With sodium hydride 1.) THF, RT, 1 h, 2.) THF, 20 min; Multistep reaction;

2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) → 2,2,5-trimethylcyclohept-4-en-1-one (19822-67-4) + (4E,6E)-2,6-Dimethyl-octa-4,6-dien-3-one (91056-18-7)

Conditions	Yield
With potassium hydrogensulfate at 200℃; for 0.5h;	A 0.7 % Chromat. B 41 % Chromat.

carbon disulfide (75-15-0) + 2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) → xanthate of 1-(5-ethenyl-5-methyl-2-tetrahydrofuranyl)-1-methylethanol (97277-68-4)

Conditions	Yield
With sodium hydride 1.) THF; Multistep reaction;

2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) → 2,2,5-trimethylcyclohept-4-en-1-one (19822-67-4)

Conditions	Yield
Multi-step reaction with 3 steps 1: 1.) NaH / 1.) THF, RT, 1 h, 2.) THF, 20 min 2: tetrahydrofuran / 0.33 h 3: 200 °C View Scheme
Multi-step reaction with 4 steps 1: 1.) NaH / 1.) THF, RT, 1 h, 2.) THF, 20 min 2: tetrahydrofuran / 0.33 h 3: 200 °C 4: 44 percent / RhCl3*3H2O, Na2CO3 / 10 h / 200 °C View Scheme

2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) → 2-methyl-5-(prop-1-en-2-yl)-2-vinyltetrahydrofuran (13679-86-2)

Conditions	Yield
Multi-step reaction with 3 steps 1: 1.) NaH / 1.) THF, RT, 1 h, 2.) THF, 20 min 2: tetrahydrofuran / 0.33 h 3: 200 °C View Scheme

2-methyl-5-(2'-propyl-2'-hydroxy)-2-vinyltetrahydrofuran (60047-17-8) → xanthate of 1-(5-ethenyl-5-methyl-2-tetrahydrofuranyl)-1-methylethanol (97277-68-4)

Conditions	Yield
Multi-step reaction with 2 steps 1: 1.) NaH / 1.) THF, RT, 1 h, 2.) THF, 20 min 2: tetrahydrofuran / 0.33 h View Scheme

Upstream product

• 79-21-0 peracetic acid 
• 126-91-0 linalool 
• 78-70-6 3,7-dimethylocta-1,6-dien-3-ol 
• 128344-89-8 anti-N-<1-(5-ethenyltetrahydro-5-methylfuran-2-yl)-1-methylethoxy>-2,2,6,6-tetramethylpiperidine 
• 128344-89-8 syn-N-<1-(5-ethenyltetrahydro-5-methylfuran-2-yl)-1-methylethoxy>-2,2,6,6-tetramethylpiperidine 
• 16262-93-4 5,6-epoxy-6-methyl-2-heptanone 
• 1826-67-1 vinyl magnesium bromide 
• 40036-54-2 (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-en-1-ol 
• 106-24-1 Geraniol 
• 123-35-3 7-methyl-3-methene-1,6-octadiene 
• 85217-73-8 (Z)-3,7-dimethylocta-2,6-dien-1-yl methyl carbonate 
• 106-25-2 Nerol 
• 188579-26-2 Carbonic acid (E)-6,7-dihydroxy-3,7-dimethyl-oct-2-enyl ester ethyl ester 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 

Downstream Products

• 1073-11-6 5-methyl-5-vinyl-dihydro-furan-2-one 
• 19822-67-4 2,2,5-trimethylcyclohept-4-en-1-one 
• 91056-18-7 (4E,6E)-2,6-Dimethyl-octa-4,6-dien-3-one 
• 56469-39-7 acetoxy linalool oxide 
• 13679-86-2 2-methyl-5-(prop-1-en-2-yl)-2-vinyltetrahydrofuran 

Relevant articles and documents

One-pot synthesis at room temperature of epoxides and linalool derivative pyrans in monolacunary Na7PW11O39-catalyzed oxidation reactions by hydrogen peroxide

In this work, we describe a new one-pot synthesis route of valuable linalool oxidation derivatives (i.e., 2-(5-methyl-5-vinyltetrahydrofuran-2-yl propan-2-ol) (1a)), 2,2,6-trimethyl-6-vinyltetrahydro-2H-pyran-3-ol (1b) and diepoxide (1c), using a green oxidant (i.e., hydrogen peroxide) under mild conditions (i.e., room temperature). Lacunar Keggin heteropolyacid salts were the catalysts investigated in this reaction. Among them, Na7PW11O39 was the most active and selective toward oxidation products. All the catalysts were characterized by FT-IR, TG/DSC, BET, XRD analyses and potentiometric titration. The main reaction parameters were assessed. Special attention was dedicated to correlating the composition and properties of the catalysts and their activity.

Asymmetric synthesis and structure-activity studies of the fungal metabolites colletorin A, colletochlorin A and their halogenates analogues

The first asymmetric total synthesis of both enantiomers of the natural products colletorin A and colletochlorin A is presented. The proposed methodology is based on the coupling reaction between highly substituted aromatic Gilman cuprates and optically active allyl bromides, in turn obtained by Sharpless asymmetric dihydroxylation. The latter ensured a high degree of regio- and stereocontrol in the enantioselective step of the synthesis. The same synthetic strategy has been also applied for the preparation of differently halogenated synthetic analogues of colletochlorin A in high enantiomeric purity. The enantioselective synthesis of colletorin A and colletochlorin A allows to reliably assign their absolute configuration. Preliminary assessment of their herbicidal and insecticidal properties evidence the possibility to modulate the bioactivity of these compounds, highlighting its dependence on both the absolute stereochemistry and the halogen nature.

Method for preparing furan-type oxidized linalool

The invention discloses a method for preparing furan-type oxidized linalool. The method specifically comprises the following steps: firstly, at the room temperature, mixing and stirring 4H-5-(1-hydroxyl-1-methyl ethyl)-2-methyl-2-furan ethanol, paratoluensulfonyl chloride and alkali to implement reaction, after the reaction is completed, adjusting the pH value to be neutral by using an acid solution, extracting, drying and filtering; performing evaporation concentration on the filtrate so as to obtain sulfonate; adding potassium tert-butoxide and tertiary butanol into the sulfonate, and performing reaction at 70-80 DEG C so as to obtain a crude product; and performing purification treatment on the crude product, thereby obtaining the furan-type oxidized linalool. The method disclosed by the invention is easy in raw material obtaining, simple in preparation process, convenient to operate, relatively low in production cost and applicable to industrial production.