13733-51-2

Basic information

• Product Name: (4-tert-butylcyclohexylidene)acetic acid
• Synonyms: (4-tert-Butylcyclohexylidene)acetic acid; acetic acid, 2-[4-(1,1-dimethylethyl)cyclohexylidene]-
• CAS NO: 13733-51-2
• Molecular Formula: C₁₂H₂₀O₂
• Molecular Weight: 196.286
• Mol File: 13733-51-2.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 314.681°C at 760 mmHg
• Flash Point: 219.398°C
• Density: 1.064g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.545
• CAS DataBase Reference: (4-tert-butylcyclohexylidene)acetic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (4-tert-butylcyclohexylidene)acetic acid(13733-51-2)
• EPA Substance Registry System: (4-tert-butylcyclohexylidene)acetic acid(13733-51-2)

Safety Data

• Hazardous Substances Data: 13733-51-2(Hazardous Substances Data)

Usage

Description

(4-tert-butylcyclohexylidene)acetic acid is a complex chemical compound derived from cyclohexylideneacetic acid, distinguished by the presence of a bulky tert-butyl group. (4-tert-butylcyclohexylidene)acetic acid features a unique structural composition, which endows it with potential biological activities and makes it a promising candidate for various applications.

Uses

Used in Organic Synthesis:
(4-tert-butylcyclohexylidene)acetic acid is utilized as a precursor in organic synthesis, playing a crucial role in the creation of other related compounds. Its unique structural features contribute to its effectiveness in this application.
Used in Pharmaceutical Industry:
Within the pharmaceutical sector, (4-tert-butylcyclohexylidene)acetic acid is used as a reagent for the preparation of various compounds. Its potential biological activities and unique structure make it a valuable asset in the development of new drugs and treatments.
Used in Agrochemical Industry:
(4-tert-butylcyclohexylidene)acetic acid also holds potential in the agrochemical industry, where it can be employed in the development of new products. Its specific structural attributes and possible biological activities may contribute to the creation of innovative solutions for agricultural challenges.
Further Research:
While (4-tert-butylcyclohexylidene)acetic acid shows promise in these areas, additional research is necessary to fully comprehend its properties and potential uses. This will enable a more comprehensive understanding of its capabilities and facilitate its integration into various industries.

Upstream product

• 54280-91-0 1-<(ethoxycarbonyl)methyl>-4-tert-butylcyclohexanol 
• 116468-86-1 cis 1-bromo-4-tert-butylcyclohexyl acetic acid 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 28835-96-3 (4-tert-butylcyclohexylidene)acetic acid 
• 129518-99-6 ethyl (4-tert-butylcyclohexylidene)acetate 
• 116468-85-0 cis 1-chloro-4-tert-butylcyclohexyl acetic acid 
• 123992-62-1 ethyl (ξ-acetoxy-4β-tert-butyl-1-cyclohexyl)acetate 
• 13278-24-5 acide hydroxy-1 tertiobutyl-4 cyclohexane-acetique 

Downstream Products

• 56300-88-0 2-(4-tert-butylcyclohexylidene)acetaldehyde 
• 123992-77-8 1-(diazoacetonylidene)-4-tert-butylcyclohexane 
• 41498-18-4 2-(4-(tert-butyl)cyclohexylidene)ethanol 
• 41498-18-4 2-(4-tert-Butyl-cyclohexylidene)-ethanol 
• 85048-19-7 (aR)-(-)-(4-tert-butylcyclohexylidene)ethanol 
• 56300-88-0 (4-tert-Butyl-cyclohexylidene)-acetaldehyde 
• 56300-88-0 (aR)-(-)-(4-tert-butylcyclohexylidene)acetaldehyde 
• 116468-86-1 cis 1-bromo-4-tert-butylcyclohexyl acetic acid 
• 116468-85-0 cis 1-chloro-4-tert-butylcyclohexyl acetic acid 
• 110840-33-0 1-Allylidene-4-tert-butyl-cyclohexane 
• 110840-33-0 (aR)-(+)-(4-tert-butylcyclohexylidene)propene 
• 85164-98-3 C-((1R,4aS,10aR)-7-Isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydro-phenanthren-1-yl)-methylamine; compound with (4-tert-butyl-cyclohexylidene)-acetic acid 

Relevant articles and documents

First catalytic enantioselective proton abstraction using chiral aikoxides

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DERACEMIZATION OF AXIALLY DISSYMMETRIC COMPOUNDS BY ENANTIOSELECTIVE DEHYDROHALOGENATION USING CHIRAL LITHIUM AMIDES -II-

New findings about deracemization of unsaturated carboxylic acids 1 by enantioselective dehydrohalogenation of prochiral species 2 by chiral lithium amides leading to axially dissymmetric compounds with 80percent e.e. are reported.The role of the structure of the prochiral hydrochlorinated intermediate is discussed.An example of axial to central chirality transfer is described. (1a -> 3)

A New, General Cyclopentenone Synthesis

A new synthesis of cyclopentenones, involving an Rh(II)-catalyzed, intramolecular carbon-hydrogen insertion of diazomethyl ketones derived from α,β-unsaturated acids, is described.