137492-80-9

Upstream product

• 106-99-0 buta-1,3-diene 
• 624-49-7 dimethylfumarate 
• 186581-53-3 diazomethane 
• 51096-08-3 (1S,2S)-cyclohex-4-ene-1,2-dicarboxylic acid 
• 67-56-1 methanol 
• 135616-40-9 (R,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine 
• 147396-58-5 buta-2,3-dien-1-yl 4-methylbenzenesulfonate 
• 109-88-6 magnesium methanolate 
• 141435-12-3 (1S,6S)-6-(2-oxooxazolidine-3-carbonyl)-cyclohex-3-enecarboxylic acid methyl ester 
• 23055-10-9 1,4-dimethyl but-2-enedioate 

Downstream Products

• 15679-27-3 (4S,5S)-4,5-bis(hydroxymethyl)cyclohexene 
• 371974-81-1 (1S,2S,4R,5S)-4,5-Dihydroxy-cyclohexane-1,2-dicarboxylic acid dimethyl ester 
• 67312-13-4 ((1R,6S)-6-Benzyloxymethyl-cyclohex-3-enyl)-acetonitrile 
• 66251-12-5 ((1R,6S)-6-Benzyloxymethyl-cyclohex-3-enyl)-acetic acid 
• 66251-11-4 Toluene-4-sulfonic acid (1S,6S)-6-benzyloxymethyl-cyclohex-3-enylmethyl ester 
• 67337-17-1 ((1S,6S)-6-(benzyloxymethyl)cyclohex-3-enyl)methanol 
• 371974-84-4 (1S,2S,4R,5S)-4-Allyloxy-5-hydroxy-cyclohexane-1,2-dicarboxylic acid dimethyl ester 

Relevant academic research and scientific papers

Enantioselective Diels-Alder reactions of optically active (buta-1,3-dien-2-yl)(salen)cobalt(iii) complexes

The syntheses of two optically active (buta-1,3-dien-2-yl)(salen)Co complexes are reported. These dienyl complexes undergo Diels-Alder reactions with high enantioselectivity with a variety of dienophiles. One of the (salen)Co-substituted Diels-Alder cyclo

Enantioselective Diels-Alder Reactions of Carboxylic Ester Dienophiles Catalysed by Titanium-Based Chiral Lewis Acid

A new titanium-based chiral Lewis acid 1 has been developed using (1R,2R)-1,2-bis-(2-methoxyphenyl)-ethane-1,2-diol as a chiral vicinal diol ligand. This chiral catalyst was found to exhibit uniformly high enantioselectivity towards carboxylic ester dienophiles in Diels-Alder reactions. The chiral vicinal ligand (1R,2R)-1,2-bis-(2-methoxyphenyl)-ethane-1,2-diol is inexpensive and is easily accessible.

Synthesis, conformational studies and mannosidase stability of a mimic of 1,2-mannobioside

Dimethyl (1S,2S,4S,5S)-4-allyloxy-5-(α-mannosyloxy)cyclohexane-1,2- dicarboxylate (3) was designed as a structural mimic of α(1,2)mannobioside (1). Its synthesis and structural analysis by NMR spectroscopy and molecular modelling are described. The result

Stereoselective synthesis of conformationally constrained cyclohexanediols: A set of molecular scaffolds for the synthesis of glycomimetics

The practical, stereoselective synthesis of the three diastereoisomeric 1,2-trans-dicarboxy-4,5-cyclohexanediols 1-3 (DCCHDs) is described, starting from a common precursor, easily available in both enantiomeric forms. The regioselective derivatization of all functional groups of 1 is also reported. The three DCCHDs are locked in a single chair conformation and thus can be used to mimic vicinally disubstituted monosaccharides of any relative configuration.

Adenine and guanine derivatives for the treatment of hepatitis virus infections

A novel nucleic acid derivative represented by the following general formula (I) and physiologically acceptable salt thereof which are expected to have an antiviral activity: STR1 wherein B represents a nucleic acid base derivative; A1 and Asu