1380310-80-4Relevant articles and documents
Nickel-Catalyzed Direct Coupling of Allylic Alcohols with Organoboron Reagents
Wang, Gaonan,Gan, Yi,Liu, Yuanhong
supporting information, p. 916 - 920 (2018/09/22)
The direct coupling of allylic alcohols with arylboronic acids or their derivatives catalyzed by Ni(cod)2 in the presence of a catalytic amount of base has been developed. A wide variety of allylic substrates or arylboronic acids turned out to be applicable to this catalytic system. The present method does not require the use of ligands for stabilizing the nickel catalyst in most cases or additional activators for activation of allylic alcohols.
Nickel-Catalyzed Regioselective Reductive Cross-Coupling of Aryl Halides with Polysubstituted Allyl Halides in the Presence of Imidazolium Salts
Zhang, Zhan,Xu, Lijun,Chen, Zhengkai,Liu, Zhubo,Miao, Maozhong,Song, Jinyu,Ren, Hongjun
, p. 2784 - 2788 (2015/12/18)
The nickel-catalyzed direct reductive cross-coupling of aryl halides with readily accessible polysubstituted allyl halides provides an efficient method for preparing diverse allylated arenes under mild conditions. Both allyl bromides and allyl chlorides are compatible with the transformation.
Catalytic allylic arylation of cinnamyl carbonates over palladium nanoparticles supported on a thermoresponsive polymer in water
Lee, Yongwoo,Shabbir, Saira,Lee, Sinyoung,Ahn, Hyunsoek,Rhee, Hakjune
, p. 3579 - 3583 (2015/06/25)
Poly(NIPAM-co-4-VP) undergoes a phase transition at the low critical solution temperature with a change from the hydrophilic to the hydrophobic core in a hydrophilic solvent. Palladium nanoparticles supported on such a thermoresponsive polymer support were demonstrated to catalyze the Tsuji-Trost reaction for the arylation of various cinnamyl carbonates by arylboronic acids. Therefore, a protocol developed using mild reaction conditions demonstrates the recyclability of the catalyst in an eco-friendly solvent such as water.