138124-72-8

Upstream product

• 72581-32-9 cyclohex-3-enylmethanol 
• 100-39-0 benzyl bromide 
• 138008-18-1 t-4-bromo-c-3-hydroxy-r-1-cyclohexanemethanol 
• 145827-23-2 4-<(benzyloxy)methyl>cyclohexene 
• 91108-45-1 c-3,4-epoxy-r-1-cyclohexanemethanol 
• 137946-37-3 c-5-<(benzyloxy)methyl>-t-2-chloro-r-1-cyclohexanol 
• 137946-44-2 ((1R,2R,5R)-5-Benzyloxymethyl-2-chloro-cyclohexyloxy)-trimethyl-silane 
• 19914-91-1 (1RS,4RS,5RS)-4-bromo-6-oxabicyclo<3.2.1>octan-7-one 
• 137946-34-0 c-4-<(benzyloxy)methyl>-r-1,2-epoxycyclohexane 
• 74-88-4 methyl iodide 
• 67-56-1 methanol 
• 138124-71-7 t-4-<(benzyloxy)methyl>-r-1,2-epoxycyclohexane 
• 138008-17-0 t-4-bromo-3-hydroxy-r-1-cyclohexanecarboxylic acid 

Downstream Products

• 138230-39-4 (1R,2R,4S)-4-Hydroxymethyl-2-methoxy-cyclohexanol 

Relevant academic research and scientific papers

Regiochemical control of the ring opening of 1,2-epoxides by means of chelating processes. Part 14: Regioselectivity of the opening reactions with MeOH of remote O-substituted 1,2-epoxycyclohexanes under gas-phase operating conditions

The regiochemical behavior of cyclohexene oxides bearing a remote O-functionality was determined in the gas-phase in opening reactions with MeOH, using a gaseous acid (D3/+, C(n)H5/+, Me2F+

Regiochemical Control of the Ring-Opening of 1,2-Epoxides by Means of Chelating Processes. 2. Synthesis and Reactions of the cis- and trans-Oxides of 4-cyclohexene, 3-Cyclohexenemethanol, and Methyl 3-Cyclohexenecarboxylate

The synthesis of the diastereoisomeric epoxides cis-1b-d and trans-2b-d and the products of their ring-opening by various nucleophiles are described.The results of the ring-openings of the trans-epoxides 2b-d can be rationalized by combining stereoelectro