138286-76-7

Upstream product

• 64-17-5 ethanol 
• 124-07-2 Octanoic acid 
• 2623-82-7 2-bromooctanoic acid 
• 59176-56-6 1-Methylthio-1-(trimethylsilyl)-1-octen 
• 7664-93-9 sulfuric acid 
• 106265-08-1 2-bromooctanoyl bromide 
• 83818-62-6 1-chloro-1-(phenylthio)-1-octene 

Downstream Products

• 2351-90-8 Ethyl oct-2-enoate 
• 7740-65-0 Ethyl 2-fluorooctanoate 
• 128849-99-0 2-(Acetoxy-phenyl-methyl)-octanoic acid ethyl ester 
• 188699-85-6 2-[2-({3-[(E)-2-(7-Chloro-quinolin-2-yl)-vinyl]-phenylamino}-methyl)-phenoxy]-octanoic acid ethyl ester 
• 111-14-8 oenanthic acid 
• 142-62-1 hexanoic acid 
• 302571-70-6 ethyl 2-bromo-2-hexyl-3-hydroxy-4-phenylpentanoate 
• 371227-18-8 2-[3-(4-hydroxy-phenyl)-4-oxo-4H-chromen-7-yloxy]-octanoic acid ethyl ester 
• 399551-38-3 ethyl 2-hexyl-2,3-epoxy-4-phenylpentanoate 
• 692730-87-3 ethyl 2-bromo-3-hydroxy-2-hexyl-3-phenylpropanoate 
• 212769-54-5 2-(4-methoxy-phenylsulfanyl)-octanoic acid ethyl ester 
• 35045-86-4 α-aminoheptanephosphonic acid 
• 5702-91-0 2-hexylsuccinic acid 

Relevant academic research and scientific papers

Highly selective synthesis of α-bromoesters using molecular bromine catalyzed by phosphorus

A series of α-bromoesters have been synthesized by applying Hell-Volhard-Zelinsky reaction catalyzed by phosphorus instead of usual phosphorus tribromide. An excellent regioselectivity to good yields are achieved at comparatively mild reaction conditions of an operational simplicity.

Cosmetic compositions

A composition for application to human skin to enhance elasticity contains as active ingredient a sulphur-containing compound of the general formula: in which M is hydrogen or a water-solubilising cation, X is S, and Y is alkyl or alkenyl of up to 4 carbon atoms, or else -XY is -SH.

SOLVOLYSIS OF 1-CHLORO-1-ALKENYL PHENYL SULFIDES. SYNTHESIS OF α-BROMO PHENYL THIOCARBOXYLIC ESTERS, α-BROMO ALKYL CARBOXYLIC ESTERS AND α-PHENYLTHIO METHYL CARBOXYLIC ESTERS

1-Chloro-1-alkenyl phenyl sulfides treated with bromine followed by hydrolysis or methanolysis give α-bromo phenyl thiocarboxylic esters and α-phenylthio methyl carboxylic esters.Direct oxidative solvolysis with bromine and alcohol give α-bromo alkyl carboxylic esters.

Unnatural nucleosides and nucleotides. III. Preparation of 2-14C and 4-14C labelled 5-alkyluracils and 5-alkyl-2'-deoxyuridines

2-14C Labelled 5-alkyluracils were prepared by condensation of the diethylacetals of α-formyl-carbonic acid esters with 14C-thiourea. Compounds labelled at 4-C were synthesized by condensation of the labelled carboxylic acid derivatives with thiourea. β-Anomers of 5-alkyl-2'-deoxyuridines were obtained in a fairly good radiochemical yield. Alkyl substituents ranged from methyl to tetradecyl, isopropyl and tert-butyl.