13880-55-2

Basic information

• Product Name: N,N,N,N-TETRAMETHYL-1-PHENYLMETHANEDIAMINE
• Synonyms: Toluene-a,a-diamine, N,N,N',N'-tetramethyl- (8CI);N,N,N',N'-Tetramethyltoluene-a,a-diamine; N,N,N',N'-tetramethyl-1-phenylmethanediamine
• CAS NO: 13880-55-2
• Molecular Formula: C₁₁H₁₈N₂
• Molecular Weight: 178.27
• Mol File: 13880-55-2.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 194.9°Cat760mmHg
• Flash Point: 62.4°C
• Appearance: /
• Density: 0.953g/cm³
• Vapor Pressure: 0.43mmHg at 25°C
• Refractive Index: 1.523
• CAS DataBase Reference: N,N,N,N-TETRAMETHYL-1-PHENYLMETHANEDIAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: N,N,N,N-TETRAMETHYL-1-PHENYLMETHANEDIAMINE(13880-55-2)
• EPA Substance Registry System: N,N,N,N-TETRAMETHYL-1-PHENYLMETHANEDIAMINE(13880-55-2)

Safety Data

• Hazardous Substances Data: 13880-55-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H18N2/c1-12(2)11(13(3)4)10-8-6-5-7-9-10/h5-9,11H,1-4H3

Upstream product

• 100-52-7 benzaldehyde 
• 124-40-3 dimethyl amine 
• 2083-91-2 N,N-Dimethyltrimethylsilylamine 
• 70509-10-3 1-phenyl-3-ethoxy-2-aza-1-butene 
• 95642-87-8 Benzoic Acid 1-Benzylidene-2-methylhydrazidoimine 
• 5873-90-5 methyl benzimidate hydrochloride 
• 126737-52-8 N,N-diethyl-N-methyl-4-phenyl-3-aza-3-butenylammonium iodide 
• 1749-16-2 N'-(benzylideneamino)-N,N-diethylethan-1-amine 
• 70509-19-2 N‐(2‐chloroethyl)‐1‐phenylmethanimine 
• 866-37-5 triethylgermyl dimethylamine 
• 4222-25-7 3-bromo-3-phenyl-3H-diazirine 
• 70509-12-5 1-phenyl-3-methoxy-2-aza-1-butene 
• 70509-11-4 1-phenyl-2-aza-1,3-butadiene 
• 143780-60-3 C₂₀H₂₈N₅P 

Downstream Products

• 65400-71-7 benzylidenebis(3-methyl-2-thiazolidinimine) 
• 1875-92-9 N,N-dimethylbenzylamine hydrochloride 
• 20599-34-2 4-dimethylamino-4-phenyl-1-butene 
• 61900-97-8 dl-N,N,N',N'-tetramethyl-1,2-diphenyl-1,2-ethylenediamine 
• 94533-51-4 (1RS,2SR)-N¹,N¹,N²,N²-tetramethyl-1,2-diphenylethane-1,2-diamine 
• 52853-20-0 benzylidene dimethyl ammonium chloride 
• 77664-48-3 (2,2-Dichloro-1-phenyl-vinyl)-dimethyl-amine 
• 22027-67-4 N-(α-Phenylacetamido-benzyl)-dimethylamin 
• 22027-63-0 N-(α-Benzamido-benzyl)-dimethylamin 
• 78190-58-6 2,2,2-trichloro-N,N-dimethyl-1-phenylethylamine 
• 86926-25-2 N,N,N',N'-tetramethyl-1,2-diphenylethane-1,2-diamine 
• 80465-12-9 1-benzyl-3,5-diphenyl-1H-1,2,4-triazole 
• 102714-56-7 methyl 2-(p-chlorophenylsulphinyl)-3-(N,N-dimethylamino)-3-phenylpropanoate 
• 132842-08-1 (2R,3R)-3-Dimethylamino-2-methyl-1,3-diphenyl-propan-1-one 

Relevant articles and documents

Reductive coupling of aromatic N,N-acetals using zinc and chlorotrimethylsilane

The reductive coupling of aromatic N,N-acetals and N,O-acetal activated by chlorotrimethylsilane proceeded smoothly in the presence of zinc to give the corresponding diamines in good yields.

Towards phase-transfer catalysts with a chiral anion: Inducing asymmetry in the reactions of cations

The ability of chiral anions, for example bis[1,1′-bi-2-naphtholato]borate, to induce asymmetry in the reactions of prochiral cations was investigated. Ion-pairing of a borate anion with an aziridinium ion was demonstrated by NMR spectroscopy. The additio

SYNTHESE SELECTIVE DE 1,2,4,3-TRIAZAPHOSPHOLES SUBSTITUES EN 1,5. STRUCTURE CRISTALLINE MOLECULAIRE DU 1-METHYL-5-BENZYL-4-TRIFLUOROBORO-1,2,4,3-TRIAZAPHOSPHOLE

A selective synthesis of 1,5-disubstituted 1,2,4,3-triazaphosphole 3 is described from bases of Schiff of 2-N substituted amidrazones 7.Crystalline molecular structure of a triazaphosphole complex with BF3 has been determinated by X-ray diffraction.Complexation occurs on N4 nitrogen atom. Key words: 1,2,4,3-triazaphospholes; ring contraction; 15N NMR; crystal structure.