13987-61-6

Basic information

• Product Name: TERT-BUTYLAZOMETHINE
• Synonyms: 1,1-dimethyl-n-methylene-ethylamin;2-methyl-n-methylene-2-propanamin;2-methyl-n-methylene-2-propanamine;n-methylene-t-butylamine;tert-butylformaldimine;TERT-BUTYLAZOMETHINE;N-methylene-tert-butylamine;2-Methyl-2-(methyleneamino)propane
• CAS NO: 13987-61-6
• Molecular Formula: C₅H₁₁N
• Molecular Weight: 85.15
• EINECS: 237-781-4
• Mol File: 13987-61-6.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 87℃
• Flash Point: -3℃
• Appearance: /
• Density: 0.71
• Vapor Pressure: 72.7mmHg at 25°C
• Refractive Index: 1.393
• PKA: 7.20±0.50(Predicted)
• CAS DataBase Reference: TERT-BUTYLAZOMETHINE(CAS DataBase Reference)
• NIST Chemistry Reference: TERT-BUTYLAZOMETHINE(13987-61-6)
• EPA Substance Registry System: TERT-BUTYLAZOMETHINE(13987-61-6)

Safety Data

• Hazardous Substances Data: 13987-61-6(Hazardous Substances Data)

Usage

Uses

N-tert-Butylazomethine is an important compound in synthetic chemistry such as in the synthesis of GSK369796 (N-tert-Butyl Isoquine) which is a novel 4-Aminoquinoline antimalarial drug.

InChI:InChI=1/C5H11N/c1-5(2,3)6-4/h4H2,1-3H3

Upstream product

• 50-00-0 formaldehyd 
• 75-64-9 tert-butylamine 
• 16479-80-4 2-tert-butyl-oxaziridine 
• 75-18-3 dimethylsulfide 
• 555-16-8 4-nitrobenzaldehdye 
• 52594-52-2 dimethyl(2,2'-bipyridine)platinum(II) 
• 811-98-3 d⁽⁴⁾-methanol 
• 67-56-1 methanol 
• 113776-98-0 1-adamantylidene-1-bromo-2-(tert-butylamino)ethane 
• 113776-99-1 2-adamantylidene-N-tert-butylaziridine 

Downstream Products

• 18626-93-2 C-tert.Butylamino-N-(3,5-di-tert.butylphenyl)-nitron 
• 14610-37-8 N-methyl-tert-butylamine 
• 90554-42-0 N²-tert-Butyl-N¹,N¹-dimethyl-2-phenylacrylamidine 
• 90226-77-0 3-tert.-Butyl-5-methyl-oxazolidin 
• 141564-68-3 3-{[tert-Butyl-(3,3-dimethyl-ureidomethyl)-amino]-methyl}-1,1-dimethyl-urea 
• 141564-69-4 3-{[tert-Butyl-(3,3-diethyl-ureidomethyl)-amino]-methyl}-1,1-diethyl-urea 
• 141564-70-7 3-{[tert-Butyl-(3,3-dipropyl-ureidomethyl)-amino]-methyl}-1,1-dipropyl-urea 
• 85517-81-3 N-Benzyl-N(tert.-butylamino-methyl)-formamid 
• 140628-15-5 1,5-Di-tert-butyl-3-phenyl-[1,3,5]triazinane-2-thione 
• 140628-24-6 5-tert-Butyl-1-(4-fluoro-phenyl)-[1,3,5]triazinane-2-thione 
• 140628-22-4 5-tert-Butyl-1-(4-nitro-phenyl)-[1,3,5]triazinane-2-thione 
• 53198-37-1 N-(1-Methoxymethyl)-N-nitroso-tert-butylamin 
• 138650-47-2 S,S,S-triphenyl hexahydro-1,3,5-triazine-1,3,5-triethanethioate 
• 53198-39-3 N-<(Nitrobenzoyloxy)methyl>-N-nitroso-tert-butylamin 

Relevant articles and documents

A 3-Azacyclopropanespiro-1,2-dioxetane via Singlet Oxygenation of a Methyleneaziridine

The first three-membered ring substituted spiro-1,2-dioxetane (2) has been synthesized and characterized through the singlet oxygenation of methyleneaziridine 1.Thermodynamic properties of the decomposition of 2 are as follows: K20 deg C = 11.5 s-1; Ea = 18.3 kcal/mol; ΔH(excit.) = 17.9 kcal/mol; ΔS(excit.) = 7.5 eu.The chemical properties of this novel dioxetane are compared to those of dioxetanes 11 and 12, dioxetanimine 9, and dioxetanone 10.

Method of preparing electron deficient olefins

This invention relates to a process for producing electron deficient olefins, such as 2-cyanoacrylates, using an iminium salt.

IMINIUM SALTS AND METHODS OF PREPARING ELECTRON DEFICIENT OLEFINS USING SUCH NOVEL IMINIUM SALTS

This invention relates to novel iminium salts, which may be in the form of ionic liquids, and a process for producing electron deficient olefins, such as 2-cyanoacrylates, using such an iminium salt, for instance in the form of an ionic liquid.