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14001-64-0

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14001-64-0 Usage

Chemical Properties

White solid

Uses

4,6-Dimethyl-2-(methylthio)pyrimidine is a useful reactant for the synthesis of substituted heterocycles via nickel-catalyzed cross-coupling reaction.

Check Digit Verification of cas no

The CAS Registry Mumber 14001-64-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,0,0 and 1 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 14001-64:
(7*1)+(6*4)+(5*0)+(4*0)+(3*1)+(2*6)+(1*4)=50
50 % 10 = 0
So 14001-64-0 is a valid CAS Registry Number.
InChI:InChI=1/C7H10N2S/c1-5-4-6(2)9-7(8-5)10-3/h4H,1-3H3

14001-64-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 4,6-dimethyl-2-methylsulfanylpyrimidine

1.2 Other means of identification

Product number -
Other names 2-methylmercapto-4,6-dimethylpyrimidine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14001-64-0 SDS

14001-64-0Relevant articles and documents

Regioselectivity in the amination of methylsulfanyl-substituted azines with O-mesitylenesulfonylhydroxylamine

Borodkin,Vorob'Ev,Shakirov,Shubin

, p. 911 - 916 (2010)

Reactions of O-mesitylenesulfonylhydroxylamine with 2-(methylsulfanyl) pyrazine, 2-(methylsulfanyl) pyrimidine, and 3,5-dimethyl-2-(methylsulfanyl) pyrimidines involve both sulfur and nitrogen atoms. The amination products at the sulfur atom prevail in th

SH-methylation of SH-containing heterocycles with dimethyl carbonate via phase-transfer catalytic reaction

Xie, Jian-Gang,Quan, Jing,Li, Shu-Bai,Zheng, Yan,Zhu, Li-Min

experimental part, p. 871 - 878 (2011/04/22)

A reaction of SH-containing heterocycles with dimethyl carbonate (DMC) in the presence of K2CO3 and tetrabutylammonium bromide (Bu4NBr) gave heteroaryl methyl thioethers in 44-93% yields. The reaction was carried out under mild conditions. This method provided a useful synthetic method for preparation of various heteroaryl methyl thioethers without the use of toxic methylic halides or dimethyl sulfate.

An easy and fast ultrasonic selective S-alkylation of hetaryl thiols at room temperature

Deligeorgiev, Todor,Kaloyanova, Stefka,Lesev, Nedyalko,Vaquero, Juan J.

experimental part, p. 783 - 788 (2011/10/09)

A series of 2-alkylthio derivatives of hetaryl thiols were synthesized by selective S-alkylation with alkyl halides (bromides and iodides) with ultrasonic irradiation at room temperature. The reaction was found to be generally applicable to hetaryl thiol derivatives with different substituents in the aromatic nucleus and various alkyl halides. The reaction gives high to excellent yields of products with high purity.

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