14023-10-0

Usage

Uses

Used in Chemical Catalysis:
TETRABUTYLAMMONIUM OCTACHLORODIRHENATE(III) is used as a catalyst in various chemical reactions due to its ability to facilitate and speed up the processes without being consumed in the reaction itself. Its high solubility and stability contribute to its effectiveness in this application.
Used in Electrochemical Applications:
TETRABUTYLAMMONIUM OCTACHLORODIRHENATE(III) is utilized in electrochemical applications, where it plays a crucial role in processes such as electroplating, electrosynthesis, and energy storage systems. Its properties allow for improved efficiency and performance in these areas.
Used in Advanced Electronic Devices:
TETRABUTYLAMMONIUM OCTACHLORODIRHENATE(III) is considered a potential material for the development of advanced electronic devices. Its unique properties may contribute to the creation of more efficient and innovative technologies in the electronics industry.
Used in Pharmaceutical Applications:
Although still in the exploratory stage, TETRABUTYLAMMONIUM OCTACHLORODIRHENATE(III) has shown promise as a candidate for pharmaceutical applications. Its potential use in this field could lead to the development of new drugs and therapies.
Used in Research and Development:
In the scientific community, TETRABUTYLAMMONIUM OCTACHLORODIRHENATE(III) is used as a subject of research and development to further explore its properties and discover new applications. This ongoing work may lead to breakthroughs in various industries.

InChI:InChI=1/2C16H36N.8ClH.2Re/c2*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;;;;;;;;;/h2*5-16H2,1-4H3;8*1H;;/q2*+1;;;;;;;;;2*+3/p-8/r2C16H36N.2Cl4Re/c2*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2*1-5(2,3)4/h2*5-16H2,1-4H3;;/q2*+1;2*-1

Upstream product

• 1112-67-0 tetrabutyl-ammonium chloride 
• 98-88-4 benzoyl chloride 
• 201230-82-2 carbon monoxide 
• 56-34-8 tetraethylammonium chloride 
• 7647-01-0 hydrogenchloride 
• 1643-19-2 tetrabutylammomium bromide 
• 10466-65-6 potassium perrhenate 
• 34248-10-7 trans-[Re(PPh₃)2Cl₄] 

Downstream Products

• 14099-01-5 rhenium(I) pentacarbonyl chloride 
• 58298-10-5 [Re2Cl4(μ-bis(diphenylphosphino)methane)2] 
• 33612-87-2 dirhenium(III) dichlorotetra-μ-acetate 
• 114720-23-9 α-Re2Cl4(1,2-bis(diphenylphosphino)ethane)2 
• 33270-29-0 {Re(dppe)2Cl₂}Cl 
• 85665-22-1 Re₂Cl₃((C₆H₅)2PC₅H₄N)2{(C₆H₅)(C₆H₄)(P(C₅H₄N))} 
• 88453-21-8 Re⁽³⁺⁾*3Cl^(1-)*(C₆H₅)2PC₅H₄N={ReCl₃((C₆H₅)2PC₅H₄N)} 
• 86436-61-5 Re₂Cl₄(CH₂(CH₂P(C₆H₅)2)2)2 

Relevant academic research and scientific papers

Thermodynamic properties of trans-tetrachlorodi-μ-carboxylate dirhenium(iii) complexes

In order to obtain unknown thermodynamic properties, such as enthalpy of formation, of trans-tetrachlorodi-μ-carboxylate dirhenium(iii) (trans-[Re2Cl4(RCOO)2] (R = C2H5; C3H7; (CH3)2CH; (CH3)3C)) exothermic reactions of burning in oxygen were investigated. The products of burning were studied by chemical analysis. The experimental enthalpy changes of the burning reactions of the complexes were obtained from DTA curves. The standard enthalpies of formation for trans-[Re2Cl4(RCOO)2] (R = C2H5; C3H7; (CH3)2CH; (CH3)3C) were found to be 36966, 63531, 48701 and 66350 kJ mol1 according to the second law of thermochemistry (Hesss law). The enthalpies of formation for the trans-carboxylates of dirhenium(iii) were calculated by a semiempirical method. A series of thermal stabilities for trans-tetrachlorodi-μ-carboxylate dirhenium(iii) complexes was built by considering their thermodynamic properties.

Metal carbonyl syntheses XXII. Low-pressure carbonylation of - and -. The technetium(I) and rhenium(I) complexes 2

Low pressure carbonylation (1 atm) of - or - in the presence of BH3/THF and halides X- results in the clean formation of 2 containing monovalent rhenium or technetium (M = Re, Tc, X = Cl, Br).In the case of the radioactive element technetium this low pressure synthesis is an important progress since the potential hazards of traditional high-pressure carbonylations are thus avoided.The complex 2 crystallizes in the space group P-1 with a = 10.166(2), b = 16.393(4), c = 17.243(5) Angstroem, and α = 69.27(2), β = 86.42(2), γ = 88.61(2) deg, Z = 4, and V = 2682(1) Angstroem3. 2 is a versatile precursor compound of other Re(I) and Tc(I) complexes: substitution of the halide ligands by a variety of ?-donor ligands is facile even under mild conditions.Examples include reactions with CN-tBu to yield quantitatively TcCl(CN-tBu)2(CO)3 and with a tetradentate phosphine ligand to yield the dinuclear complex .The X-ray structures of both compounds were determined.Dissolution of 2 in water under aerobic conditions results in the unusual organometallic aqua cation +, which species is stable in water for days (IR spectroscopy).Keywords: Rhenium; Technetium; Low-pressure Carbonylation; Metal Carbonyls; Structure

Metal carbonyl syntheses. XXII. Low pressure carbonylation of - and -: the technetium(I) and rhenium(I) complexes 2

Low pressure carbonylation (1 atm) of - or - in the presence of BH3-tetrahydrofuran and halides X- results in the clean formation of 2 containing monovalent rhenium or technetium (M = Re or Tc; X = Cl or Br).In the case of the radioactive element technetium this low pressure synthesis is an important progress since potential hazards of traditional high pressure carbonylations are thus avoided.The complex 2 crystallizes in the space group P with a = 10.166(2), b = 16.393(4), c = 17.243(5) Angstroem, and α = 69.27(2), β = 86.42(2), γ = 88.61(2) deg, Z = 4 and V = 2682(1) Angstroem3. 2 is a versatile precursor compound of other Re(I) and Tc(I) complexes; substitution of the halide ligands by a variety of ?-donor ligands is facile even under mild conditions.Examples include reactions with CN-tBu to yield quantitatively TcCl(CN-tBu)2(CO)3 and with a tetradentate phosphine ligand to yield the dinuclear complex .The x-ray structures of both compounds were determined.Dissolution of 2 in water under aerobic conditions results in the unusual organometallic aqua cation +; this species is stable in water for days (IR spectroscopy). Keywords: Rhenium; Technetium; Low-pressure carbonylation; Metal carbonyls; X-ray structure