14064-43-8

Basic information

• Product Name: (E)-3-Chlorostilbene
• Synonyms: (E)-1-(3-Chlorophenyl)-2-phenylethene;(E)-3-Chlorostilbene
• CAS NO: 14064-43-8
• Molecular Formula: C₁₄H₁₁Cl
• Molecular Weight: 214.69
• Mol File: 14064-43-8.mol
• Article Data: 52

Chemical Properties

• Melting Point: 73.5°C
• Boiling Point: 278.18°C (rough estimate)
• Appearance: /
• Density: 1.1475 (rough estimate)
• Refractive Index: 1.6012 (estimate)
• CAS DataBase Reference: (E)-3-Chlorostilbene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-Chlorostilbene(14064-43-8)
• EPA Substance Registry System: (E)-3-Chlorostilbene(14064-43-8)

Safety Data

• Hazardous Substances Data: 14064-43-8(Hazardous Substances Data)

Upstream product

• 108-42-9 3-chloro-aniline 
• 100-39-0 benzyl bromide 
• 587-04-2 m-Chlorobenzaldehyde 
• 14064-67-6 (Z)-1-chloro-3-styrylbenzene 
• 104-88-1 4-chlorobenzaldehyde 
• 100-44-7 benzyl chloride 
• 13246-50-9 benzylchlorotriphenylphosphorane 
• 1100-88-5 benzyltriphenylphosphonium chloride 
• 88652-80-6 (1RS,2SR)-1,2-diphenyl-2-diphenylphosphinoylmethan-1-ol 
• 100-42-5 styrene 
• 55791-39-4 1-Chloro-3-(1-chloro-2-phenyl-ethyl)-benzene 
• 6921-34-2 benzylmagnesium chloride 
• 20498-65-1 1--2-phenyl-aethanol 
• 146736-38-1 1-phenyl-1-chloro-2-(3-chlorophenyl)ethane 

Downstream Products

• 38503-22-9 trans-2-(m-chlorophenyl)-3-phenyloxirane 
• 34176-92-6 3-chloro-bibenzyl 
• 24423-11-8 2-chlorophenanthrene 
• 24079-43-4 4-chlorophenanthrene 
• 1016-78-0 3-chlorobenzophenone 
• 7498-72-8 1-(3-chlorophenyl)-2-phenylethane-1,2-dione 
• 52500-13-7 (E)-3-styrylbiphenyl 
• 1354971-08-6 1-((E)-styryl)-3-((E)-4-(trifluoromethyl)styryl)benzene 

Relevant articles and documents

Photocatalyzed Transition-Metal-Free Oxidative Cross-Coupling Reactions of Tetraorganoborates**

Readily accessible tetraorganoborate salts undergo selective coupling reactions under blue light irradiation in the presence of catalytic amounts of transition-metal-free acridinium photocatalysts to furnish unsymmetrical biaryls, heterobiaryls and arylated olefins. This represents an interesting conceptual approach to forge C?C bonds between aryl, heteroaryl and alkenyl groups under smooth photochemical conditions. Computational studies were conducted to investigate the mechanism of the transformation.

Tandem Acceptorless Dehydrogenative Coupling-Decyanation under Nickel Catalysis

The development of new catalytic processes based on abundantly available starting materials by cheap metals is always a fascinating task and marks an important transition in the chemical industry. Herein, a nickel-catalyzed acceptorless dehydrogenative coupling of alcohols with nitriles followed by decyanation of nitriles to access diversely substituted olefins is reported. This unprecedented C=C bond-forming methodology takes place in a tandem manner with the formation of formamide as a sole byproduct. The significant advantages of this strategy are the low-cost nickel catalyst, good functional group compatibility (ether, thioether, halo, cyano, ester, amino, N/O/S heterocycles; 43 examples), synthetic convenience, and high reaction selectivity and efficiency.