14288-22-3

Basic information

• Product Name: Ethanediamide, N,N'-dimethyl-N,N'-diphenyl-
• CAS NO: 14288-22-3
• Molecular Formula: C16H16N2O2
• Molecular Weight: 268.315
• Mol File: 14288-22-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Ethanediamide, N,N'-dimethyl-N,N'-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanediamide, N,N'-dimethyl-N,N'-diphenyl-(14288-22-3)
• EPA Substance Registry System: Ethanediamide, N,N'-dimethyl-N,N'-diphenyl-(14288-22-3)

Safety Data

• Hazardous Substances Data: 14288-22-3(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 201230-82-2 carbon monoxide 
• 100-61-8 N-methylaniline 
• 60-29-7 diethyl ether 
• 4285-42-1 N-phenyl-N-methylcarbamoyl chloride 
• 124-41-4 sodium methylate 
• 100-39-0 benzyl bromide 
• 2621-79-6 ethyl N-methyl-N-phenylcarbamate 
• 3155-16-6 diphenyl oxalate 
• 79-37-8 oxalyl dichloride 

Downstream Products

• 61110-50-7 N-methyl-N-phenyl-2-oxopropanamide 
• 66661-54-9 N,N'-Bis-chloromethyl-N,N'-diphenyl-oxalamide 
• 7025-95-8 N,N'-dimethyl-N,N'-diphenylethylenediamine 

Relevant articles and documents

Reagent Design and Ligand Evolution for the Development of a Mild Copper-Catalyzed Hydroxylation Reaction

Parallel synthesis and mass-directed purification of a modular ligand library, high-throughput experimentation, and rational ligand evolution have led to a novel copper catalyst for the synthesis of phenols with a traceless hydroxide surrogate. The mild reaction conditions reported here enable the late-stage synthesis of numerous complex, druglike phenols.

Sodium Metal Promoted Condensations of Carbamates

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Carbamoylation using the CO-containing Copper Complex derived from Lithium N-methylanilide

Lithium N-methylanilide, prepared from N-methylaniline and n-butyllithium, readily absorbed CO at atmospheric pressure in the presence of cuprous iodide to produce a CO-containing copper complex.Treatment of this complex with organic halides gave the corresponding amides in good yields.Keywords - carbonylation; carbamoylation; carbon monoxide; cuprous iodide; lithium N-methylanilide