1435-63-8

Upstream product

• 95-48-7 ortho-cresol 
• 456-27-9 4-nitrobenzenediazonium tetrafluoroborate 
• 2835-99-6 4-amino-3-methylphenol 
• 2835-96-3 4-amino-2-methylphenol 
• 100-01-6 4-nitro-aniline 
• 3019-89-4 sodium 3-methylphenoxide 
• 2724-87-0 3-Methyl-4-(2-nitro-phenylazo)-phenol 
• 636-21-5 o-toluidine hydrochloride 
• 100-05-0 4-nitrobenzenediazonium chloride 
• 127-09-3 sodium acetate 
• 4549-72-8 sodium o-cresolate 
• 621-66-9 4-hydroxy-3-methyl-azobenzene 
• 40078-29-3 4-nitro-benzenediazo hydroxide 
• 553-97-9 2-Methyl-1,4-benzoquinone 

Downstream Products

• 92555-16-3 2-acetoxy-5-(4-nitro-phenylazo)-toluene 
• 2835-96-3 4-amino-2-methylphenol 
• 553-97-9 2-Methyl-1,4-benzoquinone 

Relevant academic research and scientific papers

Photo-Responsive Behavior of Azobenzene Based Polar Hockey-Stick-Shaped Liquid Crystals

A study on the photoswitching behavior of azobenzene-based polar hockey-stick-shaped liquid crystals (HSLCs) has been presented. Two new series of five phenyl rings based polar HSLCs have been designed and synthesized. Solution state photoisomerization of

Effect of exchange of terminal substituents on the mesophase behavior of laterally methyl substituted phenyl azo benzoates in pure and mixed systems

Two groups of the formulae, 4-(4′-hexyloxy)phenylazo-2-(and 3)methyl phenyl-4″-substituted benzoates (Ia-e and IIa-e) were prepared and investigated for their mesophase behavior. Each group consists of five derivatives that differ fr

Effects of different terminal substituents on the mesomorphic behavior of some azo-Schiff base and azo-ester-based liquid crystals

In order to investigate the influence of the terminal substitution on mesomorphism, two new series of azo-Schiff base and azo-ester liquid crystals having the following structures have been synthesized. All the compounds possess mesomorphic properties. In series A compounds A1 and A3 exhibit only a nematic mesophase, whereas compounds A2, A4, A5, A6, A7, A8, A9, and A10 exhibit a smectic as well as a nematic phase. In series B compounds B1 to B9 exhibit only a nematic mesophase, and compounds B10 and B11 exhibit a smectic as well as a nematic phase, but compound B12 exhibits only a smectic phase. All these compounds were characterized by elemental analyses and spectroscopic techniques (Fourier transform infrared [FTIR], 1H nuclear magnetic resonance [NMR], and mass spectroscopy). Their mesomorphic properties were measured by optical polarized light microscopy and differential scanning calorimetry (DSC). Copyright Taylor & Francis Group, LLC.

MECHANISM OF AZO COUPLING. VI. REACTIONS OF THE p-NITROBENZENEDIAZONIUM ION WITH (PHENYLAZO)PHENOL AND ITS DERIVATIVES

According to the results of elemental analysis, high-performance liquid chromatography, and NMR, UV, and IR spectroscopy the preparatively isolated products of the reactions of the p-nitrobenzenediazonium ion with p-(phenylazo)phenol and its derivatives are derivatives of 4,4-bis(p-nitrophenylazo)-2,5-cyclohexadien-1-one.The products are stable in the solid state and in neutral media.In acid and alkaline media they are split with the formation of the nitrobenzenediazonium ion and the corresponding p-(phenylazo)phenols.The product with a cyclohexadienone structure is regarded as a model of the second of the two successively formed intermediate complexes in the azo coupling.