14366-59-7 Usage
Uses
Different sources of media describe the Uses of 14366-59-7 differently. You can refer to the following data:
1. Isopropyl 2-Isopropylphenyl Ether is used as a rearrangement isopropoxybenzene catalyst for the preparation of o-alkylated phenols. Isopropyl 2-Isopropylphenyl Ether is used in the preparation of potent subtype-selective retinoid x receptor (RXR) agonist.
2. Isopropyl 2-Isopropylphenyl (Propofol EP Impurity K) Ether is used as a rearrangement isopropoxybenzene catalyst for the preparation of o-alkylated phenols. Isopropyl 2-Isopropylphenyl Ether is used in the preparation of potent subtype-selective retinoid x receptor (RXR) agonist.
Check Digit Verification of cas no
The CAS Registry Mumber 14366-59-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,3,6 and 6 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 14366-59:
(7*1)+(6*4)+(5*3)+(4*6)+(3*6)+(2*5)+(1*9)=107
107 % 10 = 7
So 14366-59-7 is a valid CAS Registry Number.
14366-59-7Relevant articles and documents
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Ohno,A. et al.
, p. 467 - 470 (1971)
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The selective reaction of aryl halides with KOH: Synthesis of phenols, aromatic ethers, and benzofurans
Anderson, Kevin W.,Ikawa, Takashi,Tundel, Rachel E.,Buchwald, Stephen L.
, p. 10694 - 10695 (2007/10/03)
The direct and selective synthesis of phenols from aryl/heteroaryl halides and KOH has been achieved through the use of highly active monophosphine-based catalysts derived from Pd2dba3 and ligands L1 or L2 and the biphasic solvent system 1,4-dioxane/H2O. We have also demonstrated a one-pot method of phenol formation/alkylation for the preparation of alkyl aryl ethers from aryl halides. In many instances, this protocol overcomes limitations in existing Pd-catalyzed coupling reactions of aliphatic alcohols with aryl halides. Finally, we demonstrate that substituted benzofurans can be prepared efficiently via a Pd-catalyzed phenol formation/cyclization protocol starting from 2-chloroaryl alkynes. Copyright
