Radical cyclisation strategies to bridged systems. Regioselective construction of chiral bicyclo [2.2.2] and [3.2.1] octanes via 6-exo trig and 5-exo trig radical cyclisation reactions

DOI: 10.1016/S0040-4020(01)85623-4

Source and publish data:

Tetrahedron p. 9337 - 9354 (1992)

Update date:2022-08-04

Topics:

Authors:

Srikrishna

Hemmalini

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Article abstract of DOI:10.1016/S0040-4020(01)85623-4

Radical cyclisation reaction of the bromoenones 6 and 7, obtained from (R)-phenyl carvone 3, gave a mixture of bicyclo [2.2.2] and [3.2.1] octanones via competitive 6-exo trig and 5-exo trig modes. On the other hand, radical cyclisation reaction of the al

Full text of DOI:10.1016/S0040-4020(01)85623-4

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