14575-13-4

Basic information

• Product Name: 2-Pentanone, 4-chloro-4-methyl-
• Synonyms: 4-chloro-4-methyl-pentan-2-one;4-chloro-4-methylpentan-2-one;4-methyl-4-chloro-2-pentanone;4-Chlor-4-methyl-pentan-2-on;Methyl-(β-chlor-isobutyl)-keton;4-Chlor-4-methyl-pentanon-(2)
• CAS NO: 14575-13-4
• Molecular Formula: C6H11ClO
• Molecular Weight: 134.606
• Mol File: 14575-13-4.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 50-52 °C(Press: 14 Torr)
• Density: 0.9712 g/cm3(Temp: 15 °C)
• CAS DataBase Reference: 2-Pentanone, 4-chloro-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pentanone, 4-chloro-4-methyl-(14575-13-4)
• EPA Substance Registry System: 2-Pentanone, 4-chloro-4-methyl-(14575-13-4)

Safety Data

• Hazardous Substances Data: 14575-13-4(Hazardous Substances Data)

Upstream product

• 2598-29-0 8-acetyloxyquinoline 
• 1779-25-5 diisobutylaluminum chloride 
• 100-99-2 triisobutylaluminum 
• 75-36-5 acetyl chloride 
• 1767-39-1 butoxydiisobutylaluminum 
• 123-42-2 4-Hydroxy-4-methyl-2-pentanone 
• 67-64-1 acetone 

Downstream Products

• 92250-17-4 2-benzyl-4,4,6-trimethyl-4H-[1,3]oxazine 
• 92250-81-2 2-(4-methoxy-phenyl)-4,4,6-trimethyl-4H-[1,3]oxazine 
• 91807-11-3 4,4,6-trimethyl-2-(2-nitro-phenyl)-4H-[1,3]oxazine 
• 6341-46-4 4-benzyloxy-4-methyl-pentan-2-one 
• 7647-01-0 hydrogenchloride 
• 141-79-7 4-methyl-pent-3-en-2-one 
• 530-48-3 1,1-Diphenylethylene 
• 599-67-7 1,1-diphenylethanol 
• 27830-77-9 4,4,6-trimethyl-tetrahydro-[1,3]oxazin-2-one 
• 25201-40-5 1,1-diallylethanol 
• 1817-57-8 4-phenyl-3-butyne-2-one 
• 65844-80-6 5-Chloro-3,5-dimethyl-1-phenyl-hex-1-yn-3-ol 
• 92250-18-5 4,4,6-trimethyl-2-p-tolyl-4H-[1,3]oxazine 
• 91716-74-4 2-isopropyl-4,4,6-trimethyl-4H-[1,3]oxazine 

Relevant articles and documents

Synthesis of Pyranocyclopentaindolines Representing the Western Sections of Janthitrem B, JBIR-137, and Shearinine G

The synthesis of the ABCD tetracyclic partial structures of the fungal indole diterpenes janthitrem B, JBIR-137, and shearinine G is reported. The route starts from 5-formylated indoline that is coupled to a dihydropyran moiety, followed by Prins cyclization. A diene was obtained that was oxygenated in a divergent manner. The hydroxylated tetracyclic western half of janthitrem B was obtained in eight steps and 10 % overall yield. We also share our experience with alternative approaches passing via alkynylated precursors. This includes the gold-catalyzed cycloisomerization of a 6-ethynyl-5-prenylindoline.

New method for synthesis of ketones by the reactions of 8-(acyloxy)quinolines with organoaluminum compounds

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