14925-60-1Relevant articles and documents
New free-radical halogenations of alkanes, catalysed by N-hydroxyphthalimide. Polar and enthalpic effects on the chemo- and regioselectivity
Minisci, Francesco,Porta, Ombretta,Recupero, Francesco,Gambarotti, Cristian,Paganelli, Roberto,Pedulli, Gian Franco,Fontana, Francesca
, p. 1607 - 1609 (2007/10/03)
Reactions of alkanes with different halogenating systems are compared in order to explore the reactivity of phthalimido-N-oxyl radical in hydrogen abstraction; the importance of polar effects is emphasised.
Decyclization of chlorocyclohexanone hydroperoxides under the action of ferrous salts
Starostin,Gushchin,Ignatenko,Aleksandrov,Nikishin
, p. 133 - 136 (2007/10/03)
The decomposition of 2-chloro-, 2,2-dichloro-, and 2,6-dichloro-substituted cyclohexanone hydroperoxides on treatment with ferrous chloride and sulfate to give chloro-substituted aliphatic acids was investigated. A method for the synthesis of 2,6,6-trichlorohexanoic and 2,6,7,11-tetrachlorododecane-1,12-dioic acids was elaborated.
Reductive coupling of methyl αbromo-α-chlorocarboxylates
Boni, Monica
, p. 7263 - 7266 (2007/10/02)
CuBr-LiOCH3 in methanol efficiently promotes the reductive coupling of methyl α-bromo-α-chlorocarboxylates to dimethyl α,α′-dichloro-succinates.