15018-12-9

Basic information

• Product Name: Benzene, 1-(methoxymethyl)-2-methyl-
• CAS NO: 15018-12-9
• Molecular Formula: C9H12O
• Molecular Weight: 136.194
• Mol File: 15018-12-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(methoxymethyl)-2-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(methoxymethyl)-2-methyl-(15018-12-9)
• EPA Substance Registry System: Benzene, 1-(methoxymethyl)-2-methyl-(15018-12-9)

Safety Data

• Hazardous Substances Data: 15018-12-9(Hazardous Substances Data)

Upstream product

• 107-30-2 chloromethyl methyl ether 
• 6921-34-2 benzylmagnesium chloride 
• 95-46-5 2-methylphenyl bromide 
• 27490-32-0 tributyl(methoxymethyl)stannane 
• 16881-77-9 (dimethoxy)methylsilane 
• 529-20-4 2-methylphenyl aldehyde 
• 106020-70-6 2-[(methoxymethyl)methyl]benzaldehyde 
• 62172-88-7 2-(methoxymethyl)-benzyl alcohol 
• 70588-24-8 methyl 1-methyl-6-oxo-cyclohexa-2,4-diene-1-carboxylate 
• 865-34-9 lithium methanolate 
• 552-45-4 1-chloromethyl-2-methylbenzene 
• 119367-60-1 2-(Methoxymethyl)benzaldehyde tosylhydrazone 
• 75-65-0 tert-butyl alcohol 
• 64-17-5 ethanol 

Downstream Products

• 529-20-4 2-methylphenyl aldehyde 
• 125552-98-9 Ν-(2-methylbenzyl)benzamide 
• 529-19-1 2-Methylbenzonitrile 
• 91817-68-4 N-[(2-methylphenyl)methyl]acetamide 
• 32796-95-5 1,2-dimethylenebenzene 
• 29422-13-7 2-phenyltetralin 

Relevant articles and documents

Reductive etherification of aldehydes photocatalyzed by dicarbonyl pentamethylcyclopentadienyl iron complexes

The reductive etherification of aldehydes can be performed by the reaction with dialkylmethylsilanes in the presence of new iron(II) piano-stool catalysts of general formula Cp*Fe(CO)2Ar (Cp * = η5-C5Me5; Ar = Ph, 4-C6H4OCH3, 4-C6H4CH 3, Fc). This transformation is promoted by UV light and affords a simple route for the preparation of unsymmetrical alkyl ethers.

A convenient synthesis of methyl- and isopropyl-benzyl ethers using silver(II) oxide as reagent

Substituted bromomethyl- and chloromethylbenzenes and bis(bromomethyl) benzenes were directly converted, in high yields, to the corresponding methyl- and isopropyl-benzyl ethers by treatment with silver(II) oxide in methanol or isopropanol.

A NOVEL METHOXYMETHYLATION OF ARYL BROMIDE BY METHOXYMETHYLTRIBUTYLTIN IN THE PRESENCE OF PALLADIUM COMPLEX

The reaction of aryl bromides with methoxymethyltributyltin in the presence of a catalytic amount of dichlorobis(triphenylphosphine)palladium was found to give arylmethyl methyl ether.The reaction is a novel aromatic methoxymethylation.