29422-13-7Relevant articles and documents
Gverdtsiteli,Litvinov
, (1970)
An Improvement of the Palladium-Catalyzed [4+2] Cycloaddition of o -(Silylmethyl)benzyl Carbonates with Alkenes
Jin, Yushu,Ishizuka, Kentaro,Kuwano, Ryoichi
supporting information, p. 2488 - 2492 (2015/07/27)
The palladium complex, which is generated in situ from Pd(η 3-C3H5)Cp and tris(4-methoxy-3,5-dimethylphenyl)phosphine, catalyzed the [4+2] cycloaddition of o-(silylmethyl)benzyl carbonates with alkenes. The reaction of the
1,1-, 1,2-, and 1,4-eliminations from the corresponding dihalogenated compounds using Bu3SnSiMe3-F-
Sato, Hiroki,Isono, Naohiro,Miyoshi, Irie,Mori, Miwako
, p. 8143 - 8158 (2007/10/03)
The stannyl anion 2, generated from Me3SiSnBu3(1)6 in the presence of R4NX, CsF or TASF [(Et2N)3SSiMe3F2]7 in DMF under very mild conditions, was used for 1,1-, 1,2-,or 1,4-elimination of an aryl or vinyl halide with an appropriate leaving group at the α-, β-, or δ-position of halogen. Thus, alkylidene carbene 8 is generated from 1,1-dibalo-alkene 6 or 7 and benzyne 10 is generated from 1,2-dibromobenzene 9 and an o-quinodimethane 12 was produced from α,α'-dibromoxylene 11a.