Journal of the Chemical Society. Chemical communications p. 832 - 834 (1993)
Update date:2022-08-05
Topics:
Kingma, Irene E.
Wiersma, Marten
Baan, Juul L. van der
Balt, Sijbe
Bickelhaupt, Friedrich
et al.
Co(II)(salen) derivatives whose ethanediyl moiety carries an ω-alkenyl side chain react with oxygen and methanol or ethanol to give, via interaction between intermediate Co(III) species and the pendant olefin, alkylated products with a β-alkoxy substituted carbon bridge between cobalt and the equatorial ligand; the corresponding intermolecular reaction between Co(II)(salen) and hex-1-ene does not take place.
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