1504-68-3

Basic information

• Product Name: ethyl 2,4-dichlorocinnamate
• Synonyms: ethyl 2,4-dichlorocinnamate
• CAS NO: 1504-68-3
• Molecular Weight: 245.105
• Mol File: 1504-68-3.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: ethyl 2,4-dichlorocinnamate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2,4-dichlorocinnamate(1504-68-3)
• EPA Substance Registry System: ethyl 2,4-dichlorocinnamate(1504-68-3)

Safety Data

• Hazardous Substances Data: 1504-68-3(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 1201-99-6 trans-2,4-dichlorocinnamic acid 
• 874-42-0 2,4-dichlorobenzaldeyhde 
• 141-78-6 ethyl acetate 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 95-00-1 2,4-dichloro-benzenemethanamine 
• 1777-82-8 (2,4-dichlorophenyl)methanol 
• 105-36-2 ethyl bromoacetate 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 24045-02-1 (benzothiazole-2-sulfonyl)-acetic acid ethyl ester 
• 623-73-4 diazoacetic acid ethyl ester 
• 140-88-5 ethyl acrylate 
• 541-73-1 1,3-Dichlorobenzene 
• 1071-46-1 hydrogen ethyl malonate 

Downstream Products

• 1374855-86-3 (E)-N-(2-(4-cyclopropyl-4-hydroxypiperidin-1-yl)-4-methylquinazolin-6-yl)-3-(2,4-dichlorophenyl)acrylamide 
• 1201-99-6 trans-2,4-dichlorocinnamic acid 
• 148775-23-9 (2E)-3-(2,4-dichlorophenyl)prop-2-en-1-ol 
• 77975-44-1 2,4-dichloro-1-(3-chloro-1-propenyl)-benzene 
• 91700-87-7 7-chloro-3-(2,4-dichlorophenyl)-1,2,3,4,9,10-hexahydroacridine-1,9-dione 
• 191667-76-2 1-allyl-4-(2,4-dichloro-phenyl)-1H-pyrrole-3-carboxylic acid methyl-naphthalen-1-ylmethyl-amide 
• 191667-75-1 4-(2,4-dichloro-phenyl)-1-methyl-1H-pyrrole-3-carboxylic acid methyl-naphthalen-1-ylmethyl-amide 
• 191667-74-0 4-(2,4-dichloro-phenyl)-1H-pyrrole-3-carboxylic acid methyl-naphthalen-1-ylmethyl-amide 
• 191668-17-4 1-allyl-4-(2,4-dichloro-phenyl)-1H-pyrrole-3-carboxylic acid ethyl ester 
• 191668-30-1 1-allyl-4-(2,4-dichloro-phenyl)-1H-pyrrole-3-carboxylic acid 
• 191668-16-3 4-(2,4-dichloro-phenyl)-1-methyl-1H-pyrrole-3-carboxylic acid ethyl ester 
• 191668-29-8 4-(2,4-dichloro-phenyl)-1-methyl-1H-pyrrole-3-carboxylic acid 
• 191668-28-7 4-(2,4-Dichloro-phenyl)-1H-pyrrole-3-carboxylic acid 
• 191668-09-4 4-(2,4-Dichloro-phenyl)-1H-pyrrole-3-carboxylic acid ethyl ester 

Relevant articles and documents

Hypervalent iodine(iii) induced oxidative olefination of benzylamines using Wittig reagents

We have developed hypervalent iodine(iii) induced oxidative olefination of primary and secondary benzylamines using 2C-Wittig reagents, which provides easy access to α,β-unsaturated esters. Mild reaction conditions, good to excellent yields with high (E) selectivity, and a broad substrate scope are the key features of this reaction. We have successfully carried out the gram-scale synthesis of α,β-unsaturated esters.

Boron-Catalyzed C?C Functionalization of Allyl Alcohols

Tris(pentafluorophenyl)borane-catalyzed C?C bond functionalization of arylallyl alcohols using donor-acceptor carbenes is presented. The allylic hydroxyl group is found to assist the product formation by neighboring group participation providing a clue towards mechanistic understanding. This method can also be employed to effect homologation of allyl alcohols to homoallyl alcohols. Overall, this metal-free transformation presents a novel disconnection strategy towards carbon-carbon bond scission and formation. (Figure presented.).

S,O-Ligand-Promoted Palladium-Catalyzed C-H Functionalization Reactions of Nondirected Arenes

Pd(II)-catalyzed C-H functionalization of nondirected arenes has been realized using an inexpensive and easily accessible type of bidentate S,O-ligand. The catalytic system shows high efficiency in the C-H olefination reaction of electron-rich and electron-poor arenes. This methodology is operationally simple, scalable, and can be used in late-stage functionalization of complex molecules. The broad applicability of this catalyst has been showcased in other transformations such as Pd(II)-catalyzed C-H acetoxylation and allylation reactions.