151-05-3Relevant academic research and scientific papers
TEMPERATURE DEPENDENCE OF ACTIVATION VOLUME FOR ACETOLYSIS OF 2-ARYL-2-METHYLPROPYL TOSYLATES
Sera, Akira,Yamada, Hiroaki,Masaki, Hitoshi
, p. 1533 - 1536 (1980)
The activation volume of the acetolysis of the title compounds was found to have an unexpectedly large temperature dependence.The activation volume-temperature profile of a steep concave was observed which was responsible for the previously reported anomaly of the substituent dependence of the activation volume.
Hypervalent iodine(III)-mediated decarboxylative acetoxylation at tertiary and benzylic carbon centers
Kiyokawa, Kensuke,Okumatsu, Daichi,Minakata, Satoshi
supporting information, p. 1046 - 1050 (2019/11/11)
The decarboxylative acetoxylation of carboxylic acids using a combination of PhI(OAc)2 and I2 in a CH2Cl2/AcOH mixed solvent is reported. The reaction was successfully applied to two types of carboxylic acids containing an α-quaternary and a benzylic carbon center under mild reaction conditions. The resulting acetates were readily converted into the corresponding alcohols by hydrolysis.
L-pyrrolidine-2-carboxylic acid-4-hydrogen sulfate (supported on silica gel) as a new and efficient catalyst for acylation of alcohols, phenols and amines under solvent-free conditions
Hajjami, Maryam,Ghorbani-Choghamarani, Arash,Khani, Zahra
, p. 324 - 329 (2013/07/26)
In the present work, L-pyrrolidine-2-carboxylic acid-4-hydrogen sulfate, supported on silica gel was prepared and characterized by Mass spectroscopy, 1H NMR, 13CNMR, FT IR and elemental analysis (CHN) methods. This heterogenized catalyst can be used as an efficient catalyst for the acylation of alcohols, phenols, and amines with acetic anhydride under mild and solvent-free conditions. Simple work-up, stability of the catalyst, nontoxicity and good to high yields are the advantages of this work.
Polyvinylpolypyrrolidone-bound boron trifluoride: A highly efficient catalyst for acylation of alcohols, phenols and trimethylsilyl ethers by acetic anhydride
Mokhtary, Masoud,Qandalee, Mohammad,Najafizadeh, Faranak
experimental part, p. 389 - 393 (2012/08/28)
A highly efficient method for the acylation of alcohols, phenols and trimethylsilyl ethers with acetic anhydride is described using polyvinylpolypyrrolidone-bound boron trifluoride (PVPP-BF3) under mild and heterogeneous conditions at room temperature in good to excellent yields. The polyvinylpolypyrrolidone-boron trifluoride complex shows more water tolerant, non-corrosive and stable solid catalyst elevated Lewis acid properties.
Sonochemical synthesis of silica and silica sulfuric acid nanoparticles from rice husk ash: A new and recyclable catalyst for the acetylation of alcohols and phenols under heterogeneous conditions
Salavati-Niasari, Masoud,Javidi, Jaber
, p. 705 - 712 (2013/02/22)
Silica nanoparticles were synthesized from rice husk ash at room temperature by sonochemical method. The feeding rate of percipiteting agent and time of sonication were investigated. The nanostructure of the synthesized powder was realized by the FE-SEM photomicrograph, FT-IR spectroscopy, XRD and XRF analyses. These analytical observations have revealed that the nano-sized amorphous silica particles are formed and they are spheroidal in shape. The average particle size of the silica powders is found to be around 50 nm. The as-synthesized silica nanoparticles were subsequently modified with chlorosulfonic acid and prepared silica sulfuric acid nanoparticles, which were employed as an efficient catalyst for the acylation of alcohols and phenols with acetic anhydride in excellent yields under solvent-free conditions at room temperature. This reported method is simple, mild, and environmentally viable and catalyst can be simply recovered and reused over 9 times without any significant loss of its catalytic activity.
New porphyrin-polyoxometalate hybrid materials: Synthesis, characterization and investigation of catalytic activity in acetylation reactions
Araghi, Mehdi,Mirkhani, Valiollah,Moghadam, Majid,Tangestaninejad, Shahram,Mohammdpoor-Baltork, Iraj
, p. 11745 - 11752 (2013/02/23)
New hybrid complexes based on covalent interaction between 5,10,15,20-tetrakis(4-aminophenyl)porphyrinatozinc(ii) and 5,10,15,20- tetrakis(4-aminophenyl)porphyrinatotin(iv) chloride, and a Lindqvist-type polyoxometalate, Mo6O192-, were prepared. These new porphyrin-polyoxometalate hybrid materials were characterized by 1H NMR, FT IR and UV-Vis spectroscopic methods and cyclic voltammetry. These spectro- and electrochemical studies provided several spectral data for synthesis of these compounds. Cyclic voltammetry showed the influence of the polyoxometalate on the redox process of the porphyrin ring. The catalytic activity of tin(iv)porphyrin-hexamolybdate hybrid material was investigated in the acetylation of alcohols and phenols with acetic anhydride. The reusability of this catalyst was also investigated.
Polystyrene-bound electron-deficient tin(IV) porphyrin: A new, highly efficient, robust and reusable catalyst for acetylation of alcohols and phenols with acetic anhydride
Moghadam, Majid,Tangestaninejad, Shahram,Mirkhani, Valiollah,Mohammadpoor-Baltork, Iraj,Gharaati, Shadab
scheme or table, p. 1080 - 1087 (2012/03/11)
In the present work, tetrakis(p-aminophenyl)porphyrinatotin(IV) trifluoromethanesulfonate, [SnIV(TNH2PP)(OTf) 2], supported on chloromethylated polystyrene was prepared and characterized by elemental analysis, FT IR and diffuse reflectance UV-Vis spectroscopic methods. This new heterogenized catalyst was used for acetylation of alcohols and phenols with acetic anhydride in short reaction times and high yields. The catalyst is of high reusability and stability in the acetylation reactions and was recovered several times without loss of its initial activity and catalyst leaching.
Iron-doped single-walled carbon nanotubes as new heterogeneous and highly efficient catalyst for acylation of alcohols, phenols, carboxylic acids and amines under solvent-free conditions
Sharghi, Hashem,Jokar, Mahboubeh,Doroodmand, Mohammad Mahdi
experimental part, p. 426 - 442 (2011/04/15)
Iron-doped single-walled carbon nanotubes (Fe/SWCNTs) represent an efficient and new heterogeneous reusable catalyst for the acylation of a variety of alcohols, phenols, carboxylic acids and amines with acid chlorides or acid anhydrides under solvent-free conditions. The reactions of various primary, secondary, tertiary, and benzylic alcohols, diols, phenols, as well as aromatic and aliphatic amines give acylated adducts in good to excellent yields.
P-Toluenesulfonyl chloride as a new and effective catalyst for acetylation and formylation of hydroxyl compounds under mild conditions
Khazaei, Ardeshir,Rostami, Amin,Mantashlo, Fatemeh
experimental part, p. 1430 - 1434 (2011/10/08)
The catalytic application of p-toluenesulfonyl chloride for efficient acetylation of various types of alcohols and phenols with acetic anhydride in solvent-free conditions is reported. Also structurally diverse alcohols were formylated using formic acid based on the use of catalytic amount of p-toluenesulfonyl chloride under solvent-free condition. The reactions were carried out in short reaction time and in good to excellent yields at room temperature.
A mild and efficient method for the methoxymethylation and acetylation of alcohols promoted by benzyltriphenylphosphonium tribromide
Shirini, Farhad,Imanzadeh, Gholam Hossein,Mousazadeh, Seyyed Ali Reza,Mohammadpoor-Baltork, Iraj,Abedin, Masoumeh
experimental part, p. 1187 - 1190 (2011/10/05)
A mild and efficient method for the conversion of alcohols to their corresponding methoxymethyl ethers and acetates using benzyltriphenylphosphonium tribromide (BTPTB) as catalyst is described. All reactions were performed under completely heterogeneous reaction conditions in good to high yields.
