15151-78-7

Basic information

• Product Name: ethyl S-(4-chlorophenyl) thiolcarbonate
• Synonyms: ethyl S-(4-chlorophenyl) thiolcarbonate
• CAS NO: 15151-78-7
• Molecular Weight: 232.755
• Mol File: 15151-78-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ethyl S-(4-chlorophenyl) thiolcarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl S-(4-chlorophenyl) thiolcarbonate(15151-78-7)
• EPA Substance Registry System: ethyl S-(4-chlorophenyl) thiolcarbonate(15151-78-7)

Safety Data

• Hazardous Substances Data: 15151-78-7(Hazardous Substances Data)

Upstream product

• 140-89-6 potassium ethyl xanthogenate 
• 2028-74-2 p-chlorobenzenediazonium chloride 
• 637-87-6 1-Chloro-4-iodobenzene 
• 106-47-8 4-chloro-aniline 

Downstream Products

• 106-54-7 p-Chlorothiophenol 
• 56525-82-7 1-pyrrolidinecarbothioic acid O-ethyl ester 
• 22007-38-1 O-ethyl N-(4-methoxyphenyl)thiocarbamate 
• 3111-89-5 O-ethyl-N-phenylthiocarbamate 
• 482648-16-8 4-chlorodeuteriothiophenol 
• 55365-86-1 benzylthiocarbamic acid O-ethyl ester 
• 98-60-2 4-chlorobenzenesulfonyl chloride 
• 13343-26-5 phenyl p-chlorophenyl sulfide 
• 22001-51-0 O-ethyl N-(4-chlorophenyl)thiocarbamate 
• 5308-12-3 O-ethyl N-(4-methylphenyl)thiocarbamate 
• 936-64-1 morpholinyl thiocarbamate 

Relevant articles and documents

Synthesis of unsymmetrical sulfides using ethyl potassium xanthogenate and recyclable copper catalyst under ligand-free conditions

The synthesis of unsymmetrical sulfides has been achieved in good to excellent yields with inexpensive ethyl potassium xanthogenate via cross-coupling reaction using recyclable CuO nanoparticles under ligand-free conditions.The copper oxide nanoparticles can be recovered and reused up to five cycles without loss of activity.

Structure-Reactivity Relationships in the Aminolysis of O-Ethyl S-Aryl Dithiocarbonates in Aqueous Solution

The reactions of O-ethyl S-(X-phenyl) diothiocarbonates (X = p-Cl, p-Me, and p-MeO) with a series of secondary alicyclic amines and those of the same substrates and analogous derivatives (X = H, p-NO2, 2,4-(NO2)2 with pyrrolidine are subjected to a kinetic study in water, 25.0 deg C, ionic strength 0.2 M (KCl).The reactions of piperidine and pyrrolidine show second-order kinetics (first order in amine) with the formation of a zwitterionic tetrahedral intermediate (T+/-) as the rate-determining step.The reactions of the other amines exhibit orders in amine differentfrom one, compatible with the presence of an anionic intermediate (T-), resulting from a kinetically important proton transfer from T+/- to the amine.The rate of this proton transfer is faster than that of expulsion of arylthiolate from T+/- (k2) as evidenced by the estimation of these rate coefficients.The rate constants for formation of T+/- (k1) are obtained experimentally, and those for amine expulsion from T+/- (k-1) are estimated.Equations for k1 and k-1 are derived as functions of the basicity of the amine and leaving (aryl thiolate) groups.Comparison of the k-1 and k2 values found in the present reactions with those obtained in the aminolysis of aryl dithioacetates shows that substitution of Me by EtO as the "acyl" group of the zwitterionic tetrahedral intermediate destabilizes this species.