15232-10-7

Basic information

• Product Name: 2,5-Cyclohexadiene-1,4-dione, 2-(1-methylethyl)-
• CAS NO: 15232-10-7
• Molecular Formula: C9H10O2
• Molecular Weight: 150.177
• Mol File: 15232-10-7.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: 2,5-Cyclohexadiene-1,4-dione, 2-(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Cyclohexadiene-1,4-dione, 2-(1-methylethyl)-(15232-10-7)
• EPA Substance Registry System: 2,5-Cyclohexadiene-1,4-dione, 2-(1-methylethyl)-(15232-10-7)

Safety Data

• Hazardous Substances Data: 15232-10-7(Hazardous Substances Data)

Usage

General Description

2,5-Cyclohexadiene-1,4-dione, 2-(1-methylethyl)- is a chemical compound with the molecular formula C10H12O2. It is also known as isophorone dione and is commonly used as a precursor in the synthesis of various organic compounds. 2,5-Cyclohexadiene-1,4-dione, 2-(1-methylethyl)- is a yellow liquid at room temperature and exhibits a strong odor. It is primarily used in the production of polymers, resins, and adhesives. Additionally, it is utilized as an intermediate in the synthesis of pharmaceuticals and agrochemicals. However, it is important to note that this compound is hazardous and should be handled with caution, as it can cause irritation to the skin, eyes, and respiratory system.

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Relevant articles and documents

Progress towards metal-free radical alkylations of quinones under mild conditions

A new method for the radical alkylation of quinones is reported. Lewis basic nitrogen additives increase the efficacy of quinone alkylations from carboxylic acids using catalytic AgNO3 and Selectfluor as a mild oxidant. Electrochemical data sug

Quinone C-H Alkylations via Oxidative Radical Processes

A brief survey of radical additions to quinones is reported. Carboxylic acids, aldehydes, and unprotected amino acids are compared as alkyl radical precursors for the mono- or bis- C-H alkylation of several quinones. Two methods for radical initiation are discussed comparing inorganic persulfates and Selectfluor as stoichiometric oxidants. Kinetic analysis reveals dramatic differences in the rate of radical initiation depending on the identity of the radical precursor and oxidant. Synthetic strategies for efficiently producing alkyl-quinones are discussed in the context of selecting optimum radical precursors and initiators depending on quinone identity and functional groups present.

Catalytic asymmetric [2+2] cycloaddition between quinones and fulvenes and a subsequent stereoselective isomerization to 2,3-dihydrobenzofurans

The catalytic enantioselective [2+2] cycloaddition between quinones and fulvenes was achieved, for the first time, by the use of a chiral copper(ii) complex catalyst. The transformation afforded a series of enantiomerically enriched [6,4,5]-tricyclic cyclobutane derivatives in good yields with excellent regio- and stereoselectivities. Furthermore, the [2+2] adducts could be easily converted into formal [3+2] adducts efficiently and stereoselectively.