15261-41-3

Upstream product

• 110-82-7 cyclohexane 
• 20700-88-3 6-allyl-2,6-dimethyl-cyclohexa-2,4-dienone 
• 576-26-1 2.6-dimethylphenol 
• 64-17-5 ethanol 
• 141-52-6 sodium ethanolate 
• 106-95-6 allyl bromide 
• 71-43-2 benzene 
• 591-87-7 Allyl acetate 
• 35466-83-2 allyl methyl carbonate 
• 603-35-0 triphenylphosphine 
• 51624-16-9 (Z)-1,3-dimethyl-2-(prop-1-en-1-yloxy)benzene 

Downstream Products

• 576-26-1 2.6-dimethylphenol 
• 13037-83-7 4-allyl-2,6-dimethylphenol 
• 59365-65-0 3-(2,6-dimethyl-phenoxy)-propane-1,2-diol 
• 20700-88-3 6-allyl-2,6-dimethyl-cyclohexa-2,4-dienone 
• 72102-89-7 2,6-dimethylphenoxyacetaldehyde 
• 51624-16-9 (Z)-1,3-dimethyl-2-(prop-1-en-1-yloxy)benzene 
• 1386987-67-2 (2S,3aR,4R,5R,6R)-4,5-bis(benzyloxy)-6-[(benzyloxy)methyl]-2-(4-methoxy-3,5-dimethylbenzyl)-hexahydropyrrolo[1,2-b]-isoxazole 
• 53483-16-2 4-allyl-2,6-dimethylphenyl methyl ether 
• 1386987-65-0 C₂₃H₃₇NO₄ 
• 1386987-66-1 (2R,3aR,4R,5R,6R)-4,5-Bis(benzyloxy)-6-[(benzyloxy)methyl]-2-[(2,6-dimethylphenoxy)methyl]hexahydropyrrolo[1,2-b]-isoxazole 
• 148460-04-2 (S)-3-(2,6-dimethylphenoxy)propane-1,2-diol 
• 53012-41-2 (2,6-dimethylphenoxy)-2-propanone 
• 1355323-25-9 C₁₇H₂₆O₃ 
• 1355323-22-6 2-(2-(2,6-dimethylphenoxy)ethyl)-4,4,5,5-tetramethyl-1,3-dioxolane 

Relevant academic research and scientific papers

Nonracemic Dimethylphenyl Glycerol Ethers in the Synthesis of Physiologically Active Aminopropanols

Six regioisomeric nonracemic dimethylphenyl glycerol ethers were synthesized by asymmetric dihydroxylation of the corresponding allyl dimethylphenyl ethers. The enantioselectivity of the reaction with o-methyl derivatives was lower (down to 34% ee) than with m-methylphenyl ethers (up to 86% ee). Enantiomeric 3-(3,4-dimethylphenoxy)propane-1,2-diols were used to obtain enantiomerically pure physiologically active amino alcohols and their derivatives.

Visible-light-induced thiotrifluoromethylation of terminal alkenes with sodium triflinate and benzenesulfonothioates

An unconventional reductive quenching cycle was developed to realize the visible-light-induced thiotrifluoromethylation of terminal alkenes. CF3SO2Na was used as an easy to handle CF3 radical source to afford the desired products in moderate to good yields. Mild reaction conditions and a broad substrate scope feature in this transformation.

Building multivalent iminosugar-based ligands on calixarene cores via nitrone cycloadditions

A novel and challenging approach for the construction of multivalent iminosugar architectures directly on calixarene scaffolds is presented, which exploits multiple cycloaddition reactions of a carbohydrate-derived nitrone on diversely functionalized cali

Volatile organic compound sensing by gold nanoparticles capped with calix[4]arene ligand

Gold nanoparticles capped with calix[4]arene ligands have been designed and synthesized for highly sensitive and selective VOC sensing. Mass sensors coated with porous nanoparticle films displayed a good response toward toluene gas.

Synthesis and antioxidant activity of alkyl 3-(4-hydroxyaryl)propyl sulfides

4-Alkylthiopropylphenols were synthesized from corresponding 2,6-dialkylphenols via the allyl derivative. A comparative study of the antioxidant activity of the prepared compounds was carried out in five model systems. The rate constants for the reactions

Process for preparing aryl allyl ethers

A process for preparing an allyl ether including reacting (a) a phenolic compound with (b) an allyl carboxylate or an allyl carbonate in the presence of (c) a transition metal or rare earth metal catalyst complexed with at least one strongly bonded, non-replaceable stable ligand whereby an allyl ether is formed. The ligand of the transition metal or rare earth metal catalyst complex may be (i) an olefinic-containing ligand or aromatic-containing ligand; or (ii) a polymeric ligand or a heteroatom-containing multidentate ligand.

Process for preparing aryl allyl ethers

A process for preparing an allyl ether including reacting (a) a phenolic compound with (b) an allyl carboxylate or an allyl carbonate in the presence of (c) a transition metal or rare earth metal catalyst complexed with at least one strongly bonded, non-replaceable stable ligand whereby an allyl ether is formed. The ligand of the transition metal or rare earth metal catalyst complex may be (i) an olefinic-containing ligand or aromatic-containing ligand; or (ii) a polymeric ligand or a heteroatom-containing multidentate ligand.

Thermodynamic, spectroscopic, and density functional theory studies of allyl aryl and prop-1-enyl aryl ethers. Part 1. Thermodynamic data of isomerization

A chemical equilibration study of the relative thermodynamic stabilities of seventy isomeric allyl aryl ethers (a) and (Z)-prop-1-enyl aryl ethers (b) in DMSO solution has been carried out. From the variation of the equilibrium constant with temperature the Gibbs energies, enthalpies, and entropies of isomerization at 298.15 K have been evaluated. Because of their low enthalpies, the (Z)-prop-1-enyl aryl ethers are strongly favored at equilibrium, the Gibbs energies of the a→b isomerization ranging from -12 to -23 kJ mol-1. The entropy contribution is negligible in most reactions, but occasionally small positive values less than +10 J K-1 mol-1 of the entropy of isomerization are found. The equilibration studies were also extended to involve two pairs of related isomeric ethers with a Me substituent on C(2) of the olefinic bond. The Me substituent was found to increase the relative thermodynamic stability of the allylic ethers by ca. 3.4 kJ mol-1.

Asymmetric dihydroxylation of aryl allyl ethers

Asymmetric dihydroxylation of substituted aryl allyl ethers is described. Para-substituents are shown to favor high enantioselectivity (89-95%ee), while ortho-groups have a deleterious effect (28-63%ee). Four medicinal agents were prepared: guaifenesin (expectorant), mephenesin (muscle relaxant), chlorphenesin (antifungal) and propanolol (β-blocker).

Preparation of aromatic derivatives

Allyl derivatives of phenols, thiophenols and arylamines are prepared by contacting such aromatic reactant with an allyl lower alkyl carbonate in the presence of a molybdenum, tungsten or Group VIII metal.