1527472-98-5Relevant articles and documents
Copper-catalyzed allylation of a,a-difluoro-substituted organozinc reagents
Zemtsov, Artem A.,Kondratyev, Nikolay S.,Levin, Vitalij V.,Struchkova, Marina I.,Dilman, Alexander D.
, p. 818 - 822 (2014/04/03)
A method for the coupling of organozinc reagents, difluorocarbene, and allylic electrophiles is described. The reaction involves insertion of difluorocarbene into the carbon-zinc bond followed by copper-catalyzed allylic substitution.