15289-04-0

Upstream product

• 15295-70-2 dec-5-ynenitrile 
• 591-51-5 phenyllithium 
• 98-91-9 thiobenzoic acid 
• 18456-90-1 2-butylylcyclohexane-1,3-dione 
• 31508-12-0 non-1-en-4-yne 
• 374754-92-4 9-non-4-ynyl-9-bora-bicyclo[3.3.1]nonane 
• 380451-93-4 thiobenzoic acid S-(2-morpholin-4-yl-2-oxo-ethyl) ester 
• 109-65-9 1-bromo-butane 
• 15447-62-8 1-phenyl-hex-5-yn-1-one 

Relevant academic research and scientific papers

Enantioselective Conia-Ene-Type Cyclizations of Alkynyl Ketones through Cooperative Action of B(C6F5)3, N-Alkylamine and a Zn-Based Catalyst

An efficient and highly enantioselective Conia-ene-type process has been developed. Reactions are catalyzed by a combination of B(C6F5)3, an N-alkylamine and a BOX-ZnI2 complex. Specifically, through cooperative

Copper-Mediated, Palladium-Catalyzed Coupling of Thiol Esters with Aliphatic Organoboron Reagents

Thiol esters and B-alkyl-9-BBN derivatives couple in the presence of a copper(I) carboxylate mediator and a palladium catalyst. In contrast to copper-mediated, palladium-catalyzed cross-couplings of thioorganics with boronic acids, the current coupling reaction of 9-BBN derivatives is facilitated by the addition of a base such as Cs2CO3. Under optimized conditions, a variety of thiol esters react with different B-alkyl-9-BBN derivatives giving ketones in moderate to excellent yields.