153255-45-9

Basic information

• Product Name: (C₆H₅)2NBC₈H₁₄
• CAS NO: 153255-45-9
• Molecular Weight: 289.228
• Mol File: 153255-45-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (C₆H₅)2NBC₈H₁₄(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅)2NBC₈H₁₄(153255-45-9)
• EPA Substance Registry System: (C₆H₅)2NBC₈H₁₄(153255-45-9)

Safety Data

• Hazardous Substances Data: 153255-45-9(Hazardous Substances Data)

Upstream product

• 122-39-4 diphenylamine 
• 280-64-8 9-bora-bicyclo[3.3.1]nonane 
• 21205-91-4 9-borabicyclo[3.3.1]nonane dimer 
• 947153-43-7 ((((CH₃)2CH)2C₆H₃NC(CH₃))2CH)Ca(OC₄H₈)(N(C₆H₅)2) 
• 5856-89-3 lithium diphenylamide 
• 38050-71-4 9-methoxy-9-BBN 

Relevant articles and documents

Reactions of β-diketiminate-stabilized calcium amides with 9-borabicyclo[3.3.1]nonane (9-BBN)

The reaction of a β-diketiminate-stabilized calcium diphenylamide with the dialkylborane 9-BBN allows the synthesis of a β-diketiminate- stabilized calcium borohydride along with an amidoborane reaction coproduct via a likely σ-bond metathesis mechanism.

Alkaline-Earth-Catalyzed Dehydrocoupling of Amines and Boranes

Dehydrocoupling reactions between the boranes HBpin and 9-borabicyclo[3.3.1]nonane and a range of amines and anilines ensue under very mild reaction conditions in the presence of a simple β-diketiminato magnesium n-butyl precatalyst. The facility of the reactions is suggested to be a function of the Lewis acidity of the borane substrate, and is dictated by resultant pre-equilibria between, and the relative stability of, magnesium hydride and borohydride intermediates during the course of the catalysis.