1534-26-5

Basic information

• Product Name: 3-TRIDECANONE
• Synonyms: N-DECYL ETHYL KETONE;ETHYL N-DECYL KETONE;3-TRIDECANONE;tridecan-3-one;Decylethyl ketone
• CAS NO: 1534-26-5
• Molecular Formula: C13H26O
• Molecular Weight: 198.34
• EINECS: 216-253-7
• Mol File: 1534-26-5.mol
• Article Data: 15

Chemical Properties

• Melting Point: 31°C
• Boiling Point: 260.68°C (estimate)
• Flash Point: 26 °C
• Appearance: /
• Density: 0.8275 (estimate)
• Vapor Pressure: 0.0127mmHg at 25°C
• Refractive Index: 1.4365 (estimate)
• CAS DataBase Reference: 3-TRIDECANONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-TRIDECANONE(1534-26-5)
• EPA Substance Registry System: 3-TRIDECANONE(1534-26-5)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 1534-26-5(Hazardous Substances Data)

Usage

General Description

3-Tridecanone is a naturally occurring organic compound that belongs to the class of ketones. It is found in a variety of essential oils, including those from plants such as black pepper, ginger, and gingergrass. 3-Tridecanone has a strong, characteristic odor and is often used as a flavoring agent in the food and beverage industry. It also has potential applications in the field of agriculture, as it has been found to have insecticidal properties and may be used as a natural pesticide. Additionally, 3-Tridecanone has been studied for its antibacterial and antioxidant properties, suggesting potential uses in the pharmaceutical and cosmetic industries.

InChI:InChI=1/C13H26O/c1-3-5-6-7-8-9-10-11-12-13(14)4-2/h3-12H2,1-2H3

Upstream product

• 10467-10-4 ethylmagnesium iodide 
• 2244-07-7 undecanenitrile 
• 925-90-6 ethylmagnesium bromide 
• 2050-77-3 Iododecane 
• 75-03-6 ethyl iodide 
• 112-37-8 undecylenic acid 
• 802294-64-0 propionic acid 
• 17049-50-2 n-decyl magnesium bromide 
• 115-80-0 Triethyl orthopropionate 
• 872-05-9 1-Decene 
• 123-38-6 propionaldehyde 
• 2834-05-1 11-bromoundecanoic acid 
• 111-66-0 oct-1-ene 
• 1629-58-9 4-penten-3-one 

Downstream Products

• 10289-68-6 tridecan-3-ol 
• 94432-15-2 tridecan-3-one-(2,4-dinitro-phenylhydrazone) 

Relevant articles and documents

COBALOXIME-MEDIATED RADICAL ALKYL-NITROALKYLANION CROSS COUPLING

Anaerobic photolysis of aqueous ethanol solutions of alkyl cobaloximes RCoIII(dmgH)2py (dgmH = dimethylglyoxime monoanion) and nitroalkyl anions caused cross coupling in which an H α to the nitro was replaced with R.

Rhodium-Catalyzed Remote Isomerization of Alkenyl Alcohols to Ketones

We develop herein an efficient rhodium-catalyzed remote isomerization of aromatic and aliphatic alkenyl alcohols into ketones. This catalytic process, with a commercially available catalyst and ligand ([RhCl(cod)]2 and Xantphos), features high efficiency, low catalyst loading, good functional group tolerance, a broad substrate scope, and no (sub)stoichiometric additive. Preliminary mechanistic studies suggest that this transformation involves an iterative dissociative β-hydride elimination-migration insertion process.

Mild N-deacylation of secondary amides by alkylation with organocerium reagents

Secondary amides are a class of highly stable compounds serving as versatile starting materials, intermediates and directing groups (amido groups) in organic synthesis. The direct deacylation of secondary amides to release amines is an important transformation in organic synthesis. Here, we report a protocol for the deacylation of secondary amides and isolation of amines. The method is based on the activation of amides with Tf2O, followed by addition of organocerium reagents, and acidic work-up. The reaction proceeded under mild conditions and afforded the corresponding amines, isolated as their hydrochloride salts, in good yields. In combination with the C-H activation functionalization methodology, the method is applicable to the functionalization of aniline as well as conversion of carboxylic derivatives to functionalized ketones.