15364-56-4

Basic information

• Product Name: (DIMETHYLAMINO)ACETONE
• Synonyms: 1-(DIMETHYLAMINO)-2-PROPANONE 8%;(DIMETHYLAMINO)ACETONE 98%;(CH3)2NCH2COCH3;1-Dimethylaminoacetone;N,N-Dimethylaminoacetone;1-(DIMETHYLAMINO)-2-PROPANONE;1-DIMETHYLAMINO-2-PROPANE;(DIMETHYLAMINO)ACETONE
• CAS NO: 15364-56-4
• Molecular Formula: C₅H₁₁NO
• Molecular Weight: 101.15
• EINECS: 239-402-8
• Product Categories: Building Blocks;C3 to C6;Carbonyl Compounds;Chemical Synthesis;Ketones;Organic Building Blocks
• Mol File: 15364-56-4.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 119-120 °C(lit.)
• Flash Point: 86 °F
• Appearance: /
• Density: 0.883 g/mL at 25 °C(lit.)
• Vapor Pressure: 19.6mmHg at 25°C
• Refractive Index: n20/D 1.414(lit.)
• Storage Temp.: −20°C
• PKA: 7.37±0.28(Predicted)
• BRN: 1740823
• CAS DataBase Reference: (DIMETHYLAMINO)ACETONE(CAS DataBase Reference)
• NIST Chemistry Reference: (DIMETHYLAMINO)ACETONE(15364-56-4)
• EPA Substance Registry System: (DIMETHYLAMINO)ACETONE(15364-56-4)

Safety Data

• Hazard Codes: Xi,C
• Statements: 10-38
• Safety Statements: 23
• RIDADR: UN 1224 3/PG 3
• WGK Germany: 3
• F: 8-10-16-23
• HazardClass: 3.2
• PackingGroup: III
• Hazardous Substances Data: 15364-56-4(Hazardous Substances Data)

Usage

Biochem/physiol Actions

(Dimethylamino)acetone interacts with phenol derivatives in carbon tetrachloride and this interaction has been investigated by FT-IR spectroscopy.

InChI:InChI=1/C5H11NO/c1-5(7)4-6(2)3/h4H2,1-3H3

Upstream product

• 56-81-5 glycerol 
• 124-40-3 dimethyl amine 
• 926-64-7 N,N-Dimethylamino acetonitrile 
• 7223-38-3 N,N-Dimethylpropargylamin 
• 7664-93-9 sulfuric acid 
• 125704-60-1 1,4-bisacetonyldimethylammonio-2-butene dibromide 
• 14579-17-0 1-(Diaethyl-methyl-silyl)-4-dimethylamino-3-methyl-butin-⁽¹⁾-ol-⁽³⁾ 
• 100869-05-4 dimethyl-(2-methyl-[1,3]dioxolan-2-ylmethyl)-amine 
• 598-31-2 1-bromoacetone 
• 78-95-5 chloroacetone 
• 917-64-6 methyl magnesium iodide 
• 470-23-5 D-fructose 
• 50-99-7 D-glucose 
• 31688-77-4 4-Dimethylamino-3-methylbuta-1.2-dien 

Downstream Products

• 14123-48-9 1-dimethylamino-2-methyl-propan-2-ol 
• 5844-36-0 Acetic acid [2-dimethylamino-1-methyl-eth-(E)-ylidene]-hydrazide 
• 127218-68-2 3-Dimethylamino-4-oxo-2-phenyl-pentanoic acid methyl ester 
• 53636-17-2 (S)-1-dimethylamino-2-propanol 
• 53636-15-0 (R)-1-(dimethylamino)-2-propanol 
• 108-16-7 1-methyl-2-N,N-dimethylaminoethanol 
• 5843-21-0 [2-(N'-ethyl-hydrazino)-propyl]-dimethyl-amine 
• 5844-25-7 (2-hydrazino-propyl)-dimethyl-amine 
• 68-12-2 N,N-dimethyl-formamide 
• 114893-99-1 1-dimethylamino-3-diphenylphosphinoyl-2-methylpropan-2-ol 
• 140423-41-2 (E)-1-Dimethylamino-4-(4-methoxy-phenyl)-but-3-en-2-one 

Relevant articles and documents

Novel direct amination of glycerol over heteropolyacid-based catalysts

The direct amination of glycerol with dimethylamine (DMA) was studied over catalysts based on salts of phosphomolybdic acid. The highest yield of (dimethylamino)acetone (33%) was observed over a catalyst containing 50 wt% of Cs2.5H0.5PMo12O40 supported on a mesoporous silica. The corresponding sample showed good dispersion of the active phase leading to an increased number of available acid sites. With respect to the observed products, a reaction scheme was established explaining notably that the formation of 1,3-bis-dimethylamine-2-propanol and (dimethylamino)propanol was not possible due to the blocking of the required strong acid sites by DMA under reaction conditions.

Catalytic amination of glycerol with dimethylamine over different type ofheteropolyacid/Zr-MCM-41 catalysts

The effect of different type of heteropolyacid/Zr-MCM-41 catalysts on the catalytic amination of glycerol with dimethylamine to produce Dimethylamino-3-propanal was researched. Under the premise of their respective optimum loading amount, the specific sur

Preparation method of N-acetonyl amine compound

The invention discloses a preparation method of an N-acetonyl amine compound. The method comprises the following steps that an amine compound and glycerin are used as reaction raw materials, and in the presence of a composite catalyst and an alkali addition agent, in reaction mediums and at the reaction temperature of 80-180 DEG C, a reaction is performed for 2-48 hours in a sealed reactor so that the N-acetonyl amine compound is obtained. The method disclosed by the invention is simple, reaction conditions are mild, target products can be obtained at a low cost and at a high yield, and the used catalyst has high catalytic activity and is easy to separate and repeatedly use in a reaction system; besides, the whole process is environment-friendly, and the utilization of by-products namely the glycerin of biologic diesel oil is promoted.