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2-(Dimethylaminomethyl)-2-propanol, also known as DMAP, is a versatile tertiary amine with both basic and alcohol properties, commonly used as a catalyst and chemical reagent in various industrial and laboratory processes.

14123-48-9

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14123-48-9 Usage

Uses

Used in Pharmaceutical Industry:
2-(Dimethylaminomethyl)-2-propanol is used as a catalyst for the production of pharmaceuticals, facilitating various chemical reactions and improving the efficiency of the synthesis process.
Used in Pesticide Industry:
2-(Dimethylaminomethyl)-2-propanol is used as a catalyst in the production of pesticides, enabling the synthesis of active ingredients and enhancing the overall manufacturing process.
Used in Organic Chemicals Industry:
2-(Dimethylaminomethyl)-2-propanol is used as a catalyst for the synthesis of various organic chemicals, contributing to the development of new compounds and materials.
Used in Plastics Industry:
2-(Dimethylaminomethyl)-2-propanol is used as a stabilizer in the manufacture of plastics, improving the properties and performance of the final products.
Used in Urethane Foams Production:
2-(Dimethylaminomethyl)-2-propanol is used as an additive in the production of urethane foams, enhancing the foaming process and the characteristics of the resulting materials.
Used in Dyes and Pigments Synthesis:
2-(Dimethylaminomethyl)-2-propanol is used in the synthesis of dyes and pigments, contributing to the development of new colorants for various applications.
Used in Personal Care and Household Products:
2-(Dimethylaminomethyl)-2-propanol is used in the formulation of personal care and household products, providing functional benefits and improving product performance.

Check Digit Verification of cas no

The CAS Registry Mumber 14123-48-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,1,2 and 3 respectively; the second part has 2 digits, 4 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 14123-48:
(7*1)+(6*4)+(5*1)+(4*2)+(3*3)+(2*4)+(1*8)=69
69 % 10 = 9
So 14123-48-9 is a valid CAS Registry Number.
InChI:InChI=1/C6H15NO/c1-6(2,8)5-7(3)4/h8H,5H2,1-4H3

14123-48-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-(dimethylamino)-2-methylpropan-2-ol

1.2 Other means of identification

Product number -
Other names CL4586

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14123-48-9 SDS

14123-48-9Relevant academic research and scientific papers

Monomeric or Dimeric Aluminum Complexes as Catalysts for Cycloaddition between CO2 and Epoxides

Kim, So Han,Han, Sang Yeop,Kim, Jeong Hee,Kang, Yi Young,Lee, Junseong,Kim, Youngjo

, p. 2323 - 2329 (2015)

A monomeric aluminum complex containing aliphatic tetradentate ligand L1 (HOCMe2CH2NMeCH2CH2NMeCH2CMe2OH) was synthesized and used as a catalyst for cycloaddition between CO2 and epoxides in the presence of PPNCl as a cocatalyst. To check the effect of ligand L1, coordinated to the aluminum center, on the activity of cycloaddition, the new ligand HOCMe2CH2NMe2, which corresponds to half of L1, was systematically designed to make monomeric or dimeric aluminum complexes. Comparison of the catalytic properties of the aluminum complex containing the tetradentate ligand with those of the two related aluminum complexes containing the bidentate ligand under the same conditions revealed that the first system showed higher activity than the other two for cycloaddition between CO2 and epoxides in the presence of PPNCl, which was the best cocatalyst out of the six compounds nBu4PBr, nBu4NCl, nBu4NBr, nBu4NI, DMAP, and PPNCl. The aluminum complexes 1-3 demonstrate catalytic activity for cycloaddition between CO2 and epoxides in the presence of cocatalysts.

Heteroleptic Tin(IV) Aminoalkoxides and Aminofluoroalkoxides as MOCVD Precursors for Undoped and F-Doped SnO2 Thin Films

Daniele, Stéphane,Decams, Jean-Manuel,Guillon, Hervé,Jeanneau, Erwann,Mishra, Shashank,Verchère, Alexandre

, p. 7167 - 7180 (2020)

A series of asymmetric and potentially bidentate amino alcohols and amino fluoro alcohols (RNOH) having a different number of methyl/trifluoromethyl substituents at the α-carbon atom, [HOC(R1)(R2)CH2NMe2] (R1 = R2 = H (dmaeH); R1 = H, R2 = CH3 (dmapH); R1 = R2 = CH3 (dmampH); R1 = H, R2 = CF3 (F-dmapH); R1 = R2 = CF3 (F-dmampH)) have been used to develop new monomeric and heteroleptic tin(IV) amino(fluoro)alkoxides [Sn(OR)2(ORN)2] (R = Et, Pri, But). These new complexes, which were thoroughly characterized by spectroscopy (IR and multinuclei NMR (1H, 13C, 19F, and 119Sn)) as well as single-crystal X-ray studies on representative samples, were investigated for their thermal behavior to determine their suitability as MOCVD precursors for the deposition of metal oxide thin films. The two most suitable compounds, [Sn(OBut)2(dmamp)2] and [Sn(OBut)2(F-dmamp)2], were used in a direct liquid injection chemical vapor deposition (DLI-CVD) process to deposit undoped SnO2 and F-doped SnO2 thin films, respectively, on silicon and quartz substrates. Film growth rates at different temperatures (from 400 to 700 °C), film thickness, crystalline quality, and surface morphology were investigated. The films deposited on quartz showed high transparency (above 80%) in the visible region and low carbon contamination on the surface (11-13% from XPS), which could easily be removed completely with 2 min of Ar+ sputtering.

Heteroleptic manganese compounds as potential precursors for manganese based thin films and nanomaterials

Chung, Taek-Mo,Kim, Chang Gyoun,Lee, Ga Yeon,Lee, Sunju,Park, Bo Keun

, p. 29659 - 29667 (2020)

Heteroleptic manganese compounds, [Mn(tmhd)(TMEDA)Cl]2 (1), [Mn(tmhd)(dmamp)]2 (2), Mn2(tmhd)2(edpa)2(μ-THF) (3), [Mn(dmampea)(NEt2)]2 (4), and Mn(dmampea)(iPr-MeAMD) (5), were synthesized and characterized. Compound 5 was a volatile liquid. Structural analysis revealed that 1-4 were dimers. Compounds 1 and 3, 2, and 4 had distorted octahedral, distorted trigonal-bipyramidal, and distorted tetrahedral geometries around the Mn centers, respectively. Based on thermogravimetric analysis, the residues of 2 and 3 were expected to be MnO and Mn3O4, respectively. According to thermogravimetric analysis, 4 showed a higher residual value, whereas 5 exhibited a lower value than those expected for manganese nitrides. This journal is

Efficient Aluminum Catalysts for the Chemical Conversion of CO2 into Cyclic Carbonates at Room Temperature and Atmospheric CO2 Pressure

Kim, Yoseph,Hyun, Kyunglim,Ahn, Duseong,Kim, Ran,Park, Myung Hwan,Kim, Youngjo

, p. 4211 - 4220 (2019/08/12)

A series of dimeric aluminum compounds [Al(OCMe2CH2N(R)CH2X)]2 [X=pyridin-2-yl, R=H (PyrH); X= pyridin-2-yl, R=Me (PyrMe); X=furan-2-yl, R=H (FurH); X= furan-2-yl, R=Me (FurMe); X=thiophen-2-yl, R=H (ThioH); X= thiophen-2-yl, R=Me (ThioMe)] containing heterocyclic pendant group attached to the nitrogen catalyze the coupling of CO2 with epoxides under ambient conditions. In a comparison of their catalytic activities with those of aluminum complexes without pendant groups at N [X=H, R=H (HH); X=H, R=Me (HMe)] or with non-heterocyclic pendant groups [X=CH2CH2OMe, R=H (OMeH); X=CH2CH2NMe2, R=H (NMe2H); X=CH2CH2NMe2, R=Me (NMe2Me)], complexes containing heterocycles, in conjunction with (nBu)4NBr as a cocatalyst, show higher catalytic activities for the synthesis of cyclic carbonates under the same ambient conditions. The best catalyst system for this reaction is PyrH/(nBu)4NBr system, which gives a turnover number of 99 and a turnover frequency of 4.1 h?1, making it 14- and 20-times more effective than HH/(nBu)4NBr and HMe/(nBu)4NBr, respectively. Although there are no direct interactions between the aluminum and the heteroatoms in the heterocyclic pendants, electronic effects combined with the increased local concentration of CO2 around the active centers influences the catalytic activity in the coupling of CO2 with epoxides. In addition, PyrH/(nBu)4NBr shows broad epoxide substrate scope and seven terminal epoxides and two internal epoxides undergo the designed reaction.

Synthesis and characterization of Nickel(II) aminoalkoxides: Application to molecular precursors for MOCVD of Ni thin films

Yoo, Seung Ho,Choi, Hana,Kim, Hyo-Suk,Park, Bo Keun,Lee, Sun Sook,An, Ki-Seok,Lee, Young Kuk,Chung, Taek-Mo,Kim, Chang Gyoun

scheme or table, p. 1833 - 1839 (2011/06/25)

Novel single precursors for Ni, Ni(dmamp)2 (1), Ni(deamp) 2 (2), and Ni(emamp)2 (3), were synthesized by the metathesis reaction between [Ni(NH3)6]Cl2 and two equiv. of Na(dmamp), Na(deamp), and Na(emamp), respectively. Complexes 1-3 have been characterized by IR, 1H NMR, and 13C NMR spectroscopies, and microanalytical data, as well as single-crystal X-ray diffraction studies. Through GC/MS analysis of the gaseous species generated by the decomposition of 1, a self-reduction pathway to form metallic Ni was studied. By the metalorganic chemical vapor deposition of 1, metallic Ni hexagonal-phase thin films were obtained at 250 °C and cubic-phase thin films were obtained at 400 °C.

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