15666-75-8Relevant academic research and scientific papers
An efficient preparative route to substituted alkyl benzenesulfenates, versatile reagents for site-selective sulfenylative cyclizations
Harring, Scott R.,Livinghouse, Tom
, p. 893 - 902 (2007/10/03)
A versatile procedure for the synthesis of alkyl benzenesulfenates possessing varied patterns of nuclear substitution is described.
Mechanism of Nucleophilic Substitution Reactions of o-Nitrobenzenesulfenamides: Evidence for a Substitution Proceeding through a Sulfuranide Intermediate
Kice, John L.,Kutateladze, Andrei G.
, p. 3298 - 3303 (2007/10/02)
o-Nitrobenzenesulfenamides (1) undergo acid-catalyzed methanolysis (eq 2) in acetonitrile-methanol, affording methyl o-nitrobenzenesulfenate (2).They also undergo acid-catalyzed reaction with a thiol, giving an alkyl o-nitrophenyl disulfide (eq 3).In MeCN
