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16002-29-2

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16002-29-2 Usage

Chemical Properties

Pale yellow to colorless liquid

Check Digit Verification of cas no

The CAS Registry Mumber 16002-29-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,0,0 and 2 respectively; the second part has 2 digits, 2 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 16002-29:
(7*1)+(6*6)+(5*0)+(4*0)+(3*2)+(2*2)+(1*9)=62
62 % 10 = 2
So 16002-29-2 is a valid CAS Registry Number.

16002-29-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name methyl 2-(2-methoxy-2-oxoethyl)sulfanylacetate

1.2 Other means of identification

Product number -
Other names dimethyl thiodiglycolate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16002-29-2 SDS

16002-29-2Relevant articles and documents

Enzymatic Hydrolyses of the ?-Symmetric Dicarboxylic Diesters Bearing a Sulfinyl Group as the Prochiral Center

Tamai, Satoshi,Miyauchi, Satoru,Morizane, Chikako,Miyagi, Kaname,Shimizu, Hisashi,et al.

, p. 2381 - 2384 (1994)

Enzymatic hydrolyses of the ?-symmetric dicarboxylic diesters bearing a sulfinyl group as the prochiral center were examined by employing porcine liver esterase and porcine pancreatic lipase.Eventually, their chiral half esters were elaborately obtained as the corresponding chiral phenacyl esters.The stereochemistry of the chiral half esters was determined by the X-ray analysis and their chemical correlations.

-

Hiskey,R.G.,Harpp,D.N.

, p. 2014 - 2018 (1964)

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Scaffold Diversity Inspired by the Natural Product Evodiamine: Discovery of Highly Potent and Multitargeting Antitumor Agents

Wang, Shengzheng,Fang, Kun,Dong, Guoqiang,Chen, Shuqiang,Liu, Na,Miao, Zhenyuan,Yao, Jianzhong,Li, Jian,Zhang, Wannian,Sheng, Chunquan

, p. 6678 - 6696 (2015/09/07)

A critical question in natural product-based drug discovery is how to translate the product into drug-like molecules with optimal pharmacological properties. The generation of natural product-inspired scaffold diversity is an effective but challenging strategy to investigate the broader chemical space and identify promising drug leads. Extending our efforts to the natural product evodiamine, a diverse library containing 11 evodiamine-inspired novel scaffolds and their derivatives were designed and synthesized. Most of them showed good to excellent antitumor activity against various human cancer cell lines. In particular, 3-chloro-10-hydroxyl thio-evodiamine (66c) showed excellent in vitro and in vivo antitumor efficacy with good tolerability and low toxicity. Antitumor mechanism and target profiling studies indicate that compound 66c is the first-in-class triple topoisomerase I/topoisomerase II/tubulin inhibitor. Overall, this study provided an effective strategy for natural product-based drug discovery. (Figure Presented).

PROCESS FOR PREPARING DIALKYL THIODIGLYCOLATES

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Page/Page column 2, (2009/07/10)

A process is described for preparing alkyl thiodiglycolates of the general formula (I) [in-line-formulae]R—OOC—CH2-S—CH2-COO—R ??(I)[/in-line-formulae] where R is a radical of branched or unbranched C1 to C10-alkyl, characterized in that an alkyl haloacetate of the general formula (II) [in-line-formulae]X—CH2-COO—R ??(II)[/in-line-formulae] where X is a chlorine or bromine atom and R is as defined for compounds of the formula (I) is reacted with an aqueous solution of alkali metal sulphide or alkali metal hydrogensulphide in the presence of an aqueous pH buffer solution in the pH range between 5 and 8, optionally in the presence of a phase transfer catalyst.

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