160115-23-1Relevant articles and documents
Aluminium - SALEN complex: a new catalyst for the enantioselective Michael reaction
Iha, S. C.,Joshi, N. N.
, p. 2463 - 2466 (2001)
A new heterobimetallic complex prepared from a chiral SALEN ligand and Red-Al(R) was found to catalyse the Michael reaction between various dialkyl malonates and cycloalkenones to give products in high yields with e.e. of up to 58 percent.
Asymmetric Michael reactions of α-substituted acetates with cyclic enones catalyzed by multifunctional chiral Ru amido complexes
Ikariya, Takao,Wang, Hui,Watanabe, Masahito,Murata, Kunihiko
, p. 1377 - 1381 (2004)
Well-defined 16-electron chiral Ru amido complexes, Ru[(R,R)-diamine](η6-arene), efficiently catalyze asymmetric Michael additions of Michael donors to cyclic enones to give adducts in high yields and with excellent ee's. β-Ketoesters or nitroa
Mapping the Surface Groups of Amine-Rich Carbon Dots Enables Covalent Catalysis in Aqueous Media
Amato, Francesco,Bonchio, Marcella,Companyó, Xavier,Dell'Amico, Luca,Filippini, Giacomo,Prato, Maurizio,Ragazzon, Giulio,Rosso, Cristian,Vega-Pe?aloza, Alberto
supporting information, p. 3022 - 3037 (2020/11/03)
Carbon nanodots stand as the missing link between the molecular and the nanoscale world, owing to the unique molecular-like behavior emerging from their synthetic precursors. A converging set of analytical and spectroscopic data yields a precise inventory
Rendering classical hydrophilic enantiopure Werner salts [M(en)3]: N + n X- lipophilic (M/ n = Cr/3, Co/3, Rh/3, Ir/3, Pt/4); New chiral hydrogen bond donor catalysts and enantioselectivities as a function of metal and charge
Alvi, Scheherzad,Ganzmann, Carola,Gladysz, John A.,Hooda, Karan R.,Maximuck, William J.
, p. 3680 - 3691 (2020/04/03)
Known hydrophilic halide salts of the title compounds are converted to new lipophilic BArf- (B(3,5-C6H3(CF3)2)4-) salts. These are isolated as hydrates (Λ- or Δ-[M(en)
Enzyme-Promoted Direct Asymmetric Michael Reaction by Using Protease from Streptomyces griseus
Wu, Ling-Ling,Li, Ling-Po,Xiang, Yang,Guan, Zhi,He, Yan-Hong
, p. 2209 - 2214 (2017/07/24)
The direct asymmetric Michael addition of malonates and enones was promoted by protease from Streptomyces griseus for the first time. Yields of up to 84% with enantioselectivities of up to 98% enantiomeric excess (ee) were achieved under optimized conditi