160115-23-1

Basic information

• Product Name: (S)-(-)-3-BIS(METHOXYCARBONYL)METHYL-1-CYCLOPENTANONE
• Synonyms: (S)-(-)-3-BIS(METHOXYCARBONYL)METHYL-1-CYCLOPENTANONE
• CAS NO: 160115-23-1
• Molecular Formula: C10H14O5
• Molecular Weight: 214.22
• Mol File: 160115-23-1.mol
• Article Data: 32

Chemical Properties

• Boiling Point: 288.1±10.0 °C(Predicted)
• Appearance: /
• Density: 1.208±0.06 g/cm3(Predicted)
• PKA: 12.15±0.20(Predicted)
• CAS DataBase Reference: (S)-(-)-3-BIS(METHOXYCARBONYL)METHYL-1-CYCLOPENTANONE(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(-)-3-BIS(METHOXYCARBONYL)METHYL-1-CYCLOPENTANONE(160115-23-1)
• EPA Substance Registry System: (S)-(-)-3-BIS(METHOXYCARBONYL)METHYL-1-CYCLOPENTANONE(160115-23-1)

Safety Data

• Hazardous Substances Data: 160115-23-1(Hazardous Substances Data)

Upstream product

• 930-30-3 cyclopent-2-enone 
• 108-59-8 malonic acid dimethyl ester 
• 105-53-3 diethyl malonate 
• 67-56-1 methanol 
• 185760-71-8 (R)-3-cyclopentenone 
• 6773-29-1 dimethyl diazomalonate 
• 120-92-3 cyclopentanone 

Downstream Products

• 2630-38-8 (S)-(-)-methyl 3-oxocyclopentylacetate 
• 84621-34-1 (R)-(+)-methyl 3-oxocyclopentylacetate 
• 34130-51-3 methylester of 3-oxo-cyclopentylacetic acid 

Relevant articles and documents

Aluminium - SALEN complex: a new catalyst for the enantioselective Michael reaction

A new heterobimetallic complex prepared from a chiral SALEN ligand and Red-Al(R) was found to catalyse the Michael reaction between various dialkyl malonates and cycloalkenones to give products in high yields with e.e. of up to 58 percent.

Asymmetric Michael reactions of α-substituted acetates with cyclic enones catalyzed by multifunctional chiral Ru amido complexes

Well-defined 16-electron chiral Ru amido complexes, Ru[(R,R)-diamine](η6-arene), efficiently catalyze asymmetric Michael additions of Michael donors to cyclic enones to give adducts in high yields and with excellent ee's. β-Ketoesters or nitroa

Mapping the Surface Groups of Amine-Rich Carbon Dots Enables Covalent Catalysis in Aqueous Media

Carbon nanodots stand as the missing link between the molecular and the nanoscale world, owing to the unique molecular-like behavior emerging from their synthetic precursors. A converging set of analytical and spectroscopic data yields a precise inventory

Rendering classical hydrophilic enantiopure Werner salts [M(en)3]: N + n X- lipophilic (M/ n = Cr/3, Co/3, Rh/3, Ir/3, Pt/4); New chiral hydrogen bond donor catalysts and enantioselectivities as a function of metal and charge

Known hydrophilic halide salts of the title compounds are converted to new lipophilic BArf- (B(3,5-C6H3(CF3)2)4-) salts. These are isolated as hydrates (Λ- or Δ-[M(en)

Enzyme-Promoted Direct Asymmetric Michael Reaction by Using Protease from Streptomyces griseus

The direct asymmetric Michael addition of malonates and enones was promoted by protease from Streptomyces griseus for the first time. Yields of up to 84% with enantioselectivities of up to 98% enantiomeric excess (ee) were achieved under optimized conditi